Crystal structure of tetra­guanidinium [hexa­hydrogen hexa­arsenato(V)tetra­vanadate(V)] tetra­hydrate

The complete polyoxidometallate anion in the title compound, (CH6N3)4[H6V4As6O30]·4H2O, is generated by crystallographic inversion symmetry. The polyhedral building units are distorted VO6 octa­hedra and AsO3OH tetra­hedra. The VO6 units feature a short formal V=O double bond and are linked by a com...

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Bibliographic Details
Main Author: Harrison, William T. A.
Format: Online
Language:English
Published: International Union of Crystallography 2014
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186164/