N 1-[(1H-Imidazol-2-yl)methylidene]-N 4-phenylbenzene-1,4-diamine
The title compound, C16H14N4, is non-planar with dihedral angles between the planes of the imidazole and phenylenediamine rings of 30.66 (4)° and between the planes of the phenylenediamine and N-phenyl rings of 56.63 (7)°. In the crystal, molecules are connected by N—H⋯N hydrogen bonds, generat...
| Main Authors: | , , , |
|---|---|
| Format: | Online |
| Language: | English |
| Published: |
International Union of Crystallography
2014
|
| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120595/ |
| id |
pubmed-4120595 |
|---|---|
| recordtype |
oai_dc |
| spelling |
pubmed-41205952014-08-26 N 1-[(1H-Imidazol-2-yl)methylidene]-N 4-phenylbenzene-1,4-diamine Faizi, Md. Serajul Haque Mashrai, Ashraf Shahid, M. Ahmad, Musheer Organic Papers The title compound, C16H14N4, is non-planar with dihedral angles between the planes of the imidazole and phenylenediamine rings of 30.66 (4)° and between the planes of the phenylenediamine and N-phenyl rings of 56.63 (7)°. In the crystal, molecules are connected by N—H⋯N hydrogen bonds, generating a chain extending along the b-axis direction. The crystal structure is also stabilized by C—H⋯π interactions between N-phenyl and imidazole rings and slipped π–π stacking interactions between imidazole rings [centroid–centroid distance = 3.516 (4) Å] giving an overall two-dimensional layered structure lying parallel to (010). International Union of Crystallography 2014-06-25 /pmc/articles/PMC4120595/ /pubmed/25161587 http://dx.doi.org/10.1107/S1600536814014238 Text en © Faizi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Faizi, Md. Serajul Haque Mashrai, Ashraf Shahid, M. Ahmad, Musheer |
| spellingShingle |
Faizi, Md. Serajul Haque Mashrai, Ashraf Shahid, M. Ahmad, Musheer N 1-[(1H-Imidazol-2-yl)methylidene]-N 4-phenylbenzene-1,4-diamine |
| author_facet |
Faizi, Md. Serajul Haque Mashrai, Ashraf Shahid, M. Ahmad, Musheer |
| author_sort |
Faizi, Md. Serajul Haque |
| title |
N
1-[(1H-Imidazol-2-yl)methylidene]-N
4-phenylbenzene-1,4-diamine |
| title_short |
N
1-[(1H-Imidazol-2-yl)methylidene]-N
4-phenylbenzene-1,4-diamine |
| title_full |
N
1-[(1H-Imidazol-2-yl)methylidene]-N
4-phenylbenzene-1,4-diamine |
| title_fullStr |
N
1-[(1H-Imidazol-2-yl)methylidene]-N
4-phenylbenzene-1,4-diamine |
| title_full_unstemmed |
N
1-[(1H-Imidazol-2-yl)methylidene]-N
4-phenylbenzene-1,4-diamine |
| title_sort |
n
1-[(1h-imidazol-2-yl)methylidene]-n
4-phenylbenzene-1,4-diamine |
| description |
The title compound, C16H14N4, is non-planar with dihedral angles between the planes of the imidazole and phenylenediamine rings of 30.66 (4)° and between the planes of the phenylenediamine and N-phenyl rings of 56.63 (7)°. In the crystal, molecules are connected by N—H⋯N hydrogen bonds, generating a chain extending along the b-axis direction. The crystal structure is also stabilized by C—H⋯π interactions between N-phenyl and imidazole rings and slipped π–π stacking interactions between imidazole rings [centroid–centroid distance = 3.516 (4) Å] giving an overall two-dimensional layered structure lying parallel to (010). |
| publisher |
International Union of Crystallography |
| publishDate |
2014 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120595/ |
| _version_ |
1613120537670713344 |