N-Methyl-2-(1-methyl-3-phenylprop-2-en-1-ylidene)hydrazinecarbothioamide
In the title compound, C12H15N3S, the molecule deviates slightly from planarity, with a maximum deviation from the mean plane of the non-H atoms of 0.2756 (6) Å for the S atom and a torsion angle for the N—N—C—N fragment of −7.04 (16)°. In the crystal, molecules are linked by N—H⋯S hydrogen-bond i...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2014
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120594/ |
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pubmed-4120594 |
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oai_dc |
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pubmed-41205942014-08-26 N-Methyl-2-(1-methyl-3-phenylprop-2-en-1-ylidene)hydrazinecarbothioamide Rocha, Fillipe Vieira de Godoy Netto, Adelino Vieira Beck, Johannes Daniels, Jörg de Oliveira, Adriano Bof Organic Papers In the title compound, C12H15N3S, the molecule deviates slightly from planarity, with a maximum deviation from the mean plane of the non-H atoms of 0.2756 (6) Å for the S atom and a torsion angle for the N—N—C—N fragment of −7.04 (16)°. In the crystal, molecules are linked by N—H⋯S hydrogen-bond interactions, forming centrosymmetric dimers. Additionally, one weak intramolecular N—H⋯N hydrogen-bond interaction is observed. The crystal packing shows a herringbone arrangement viewed along the c axis. International Union of Crystallography 2014-06-21 /pmc/articles/PMC4120594/ /pubmed/25161581 http://dx.doi.org/10.1107/S1600536814013889 Text en © Rocha et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Rocha, Fillipe Vieira de Godoy Netto, Adelino Vieira Beck, Johannes Daniels, Jörg de Oliveira, Adriano Bof |
| spellingShingle |
Rocha, Fillipe Vieira de Godoy Netto, Adelino Vieira Beck, Johannes Daniels, Jörg de Oliveira, Adriano Bof N-Methyl-2-(1-methyl-3-phenylprop-2-en-1-ylidene)hydrazinecarbothioamide |
| author_facet |
Rocha, Fillipe Vieira de Godoy Netto, Adelino Vieira Beck, Johannes Daniels, Jörg de Oliveira, Adriano Bof |
| author_sort |
Rocha, Fillipe Vieira |
| title |
N-Methyl-2-(1-methyl-3-phenylprop-2-en-1-ylidene)hydrazinecarbothioamide |
| title_short |
N-Methyl-2-(1-methyl-3-phenylprop-2-en-1-ylidene)hydrazinecarbothioamide |
| title_full |
N-Methyl-2-(1-methyl-3-phenylprop-2-en-1-ylidene)hydrazinecarbothioamide |
| title_fullStr |
N-Methyl-2-(1-methyl-3-phenylprop-2-en-1-ylidene)hydrazinecarbothioamide |
| title_full_unstemmed |
N-Methyl-2-(1-methyl-3-phenylprop-2-en-1-ylidene)hydrazinecarbothioamide |
| title_sort |
n-methyl-2-(1-methyl-3-phenylprop-2-en-1-ylidene)hydrazinecarbothioamide |
| description |
In the title compound, C12H15N3S, the molecule deviates slightly from planarity, with a maximum deviation from the mean plane of the non-H atoms of 0.2756 (6) Å for the S atom and a torsion angle for the N—N—C—N fragment of −7.04 (16)°. In the crystal, molecules are linked by N—H⋯S hydrogen-bond interactions, forming centrosymmetric dimers. Additionally, one weak intramolecular N—H⋯N hydrogen-bond interaction is observed. The crystal packing shows a herringbone arrangement viewed along the c axis. |
| publisher |
International Union of Crystallography |
| publishDate |
2014 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120594/ |
| _version_ |
1613120537064636416 |