4-{[4-(Di­methyl­amino)­benzyl­idene]amino}­benzene­sulfonamide

4-{[4-(Di­methyl­amino)­benzyl­idene]amino}­benzene­sulfonamide

The title Schiff base compound, C15H17N3O2S, is non-planar with a dihedral angle of 69.88 (4)° between the planes of the benzene rings. In the crystal, pairs of N—H⋯N hydrogen bonds, between the sulfonamide nitro­gen-H atom and the azomethine N atom, link the mol­ecules into inversion dimers, formin...

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Main Authors: Durgun, Mustafa, Türkmen, Hasan, Tunç, Tuncay, Hökelek, Tuncer
Format: Online
Language:English
Published: International Union of Crystallography 2014
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051049/
id pubmed-4051049
recordtype oai_dc
spelling pubmed-40510492014-06-17 4-{[4-(Di­methyl­amino)­benzyl­idene]amino}­benzene­sulfonamide Durgun, Mustafa Türkmen, Hasan Tunç, Tuncay Hökelek, Tuncer Organic Papers The title Schiff base compound, C15H17N3O2S, is non-planar with a dihedral angle of 69.88 (4)° between the planes of the benzene rings. In the crystal, pairs of N—H⋯N hydrogen bonds, between the sulfonamide nitro­gen-H atom and the azomethine N atom, link the mol­ecules into inversion dimers, forming R 2 2(16) ring motifs. These dimers are linked by N—H⋯O hydrogen bonds, between the sulfonamide nitro­gen-H atom and one sulfonamide O atom, forming sheets lying parallel to (100). Within the sheets there are weak parallel slipped π–π inter­actions involving inversion-related benzene­sulfonamide rings [centroid–centroid distance = 3.8800 (9) Å; normal distance = 3.4796 (6) Å; slippage = 1.717 Å]. International Union of Crystallography 2014-05-31 /pmc/articles/PMC4051049/ /pubmed/24940295 http://dx.doi.org/10.1107/S1600536814012136 Text en © Durgun et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
repository_type Open Access Journal
institution_category Foreign Institution
institution US National Center for Biotechnology Information
building NCBI PubMed
collection Online Access
language English
format Online
author Durgun, Mustafa
Türkmen, Hasan
Tunç, Tuncay
Hökelek, Tuncer
spellingShingle Durgun, Mustafa
Türkmen, Hasan
Tunç, Tuncay
Hökelek, Tuncer
4-{[4-(Di­methyl­amino)­benzyl­idene]amino}­benzene­sulfonamide
author_facet Durgun, Mustafa
Türkmen, Hasan
Tunç, Tuncay
Hökelek, Tuncer
author_sort Durgun, Mustafa
title 4-{[4-(Di­methyl­amino)­benzyl­idene]amino}­benzene­sulfonamide
title_short 4-{[4-(Di­methyl­amino)­benzyl­idene]amino}­benzene­sulfonamide
title_full 4-{[4-(Di­methyl­amino)­benzyl­idene]amino}­benzene­sulfonamide
title_fullStr 4-{[4-(Di­methyl­amino)­benzyl­idene]amino}­benzene­sulfonamide
title_full_unstemmed 4-{[4-(Di­methyl­amino)­benzyl­idene]amino}­benzene­sulfonamide
title_sort 4-{[4-(di­methyl­amino)­benzyl­idene]amino}­benzene­sulfonamide
description The title Schiff base compound, C15H17N3O2S, is non-planar with a dihedral angle of 69.88 (4)° between the planes of the benzene rings. In the crystal, pairs of N—H⋯N hydrogen bonds, between the sulfonamide nitro­gen-H atom and the azomethine N atom, link the mol­ecules into inversion dimers, forming R 2 2(16) ring motifs. These dimers are linked by N—H⋯O hydrogen bonds, between the sulfonamide nitro­gen-H atom and one sulfonamide O atom, forming sheets lying parallel to (100). Within the sheets there are weak parallel slipped π–π inter­actions involving inversion-related benzene­sulfonamide rings [centroid–centroid distance = 3.8800 (9) Å; normal distance = 3.4796 (6) Å; slippage = 1.717 Å].
publisher International Union of Crystallography
publishDate 2014
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051049/
_version_ 1612098828349997056

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