2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide
The title molecule, C9H7ClN4OS, is almost planar, with an r.m.s. deviation of 0.034 (2) Å for the mean plane through all the non-H atoms. Intramolecular N—H⋯O and N—H⋯N hydrogen bonds form S(6) and S(5) ring motifs, respectively. In the crystal, molecules are assembled into inversion dimers throu...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2013
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029216/ |
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pubmed-4029216 |
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oai_dc |
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pubmed-40292162014-05-22 2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide de Bittencourt, Viviane Conceição Duarte Vicenti, Juliano Rosa de Menezes Velasques, Jecika Maciel Zambiazi, Priscilla Jussiane Gervini, Vanessa Carratu Organic Papers The title molecule, C9H7ClN4OS, is almost planar, with an r.m.s. deviation of 0.034 (2) Å for the mean plane through all the non-H atoms. Intramolecular N—H⋯O and N—H⋯N hydrogen bonds form S(6) and S(5) ring motifs, respectively. In the crystal, molecules are assembled into inversion dimers through pairs of co-operative N—H⋯Cl interactions. These dimers are connected along the b axis by N—H⋯O and N—H⋯S hydrogen bonds, generating layers parallel to (103). The layers are further connected along the a axis into a three-dimensional network, through weak π–π stacking interactions [centroid–centroid distance = 3.849 (2) Å]. International Union of Crystallography 2013-12-14 /pmc/articles/PMC4029216/ /pubmed/24855470 http://dx.doi.org/10.1107/S1600536813033369 Text en © Bittencourt et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
de Bittencourt, Viviane Conceição Duarte Vicenti, Juliano Rosa de Menezes Velasques, Jecika Maciel Zambiazi, Priscilla Jussiane Gervini, Vanessa Carratu |
| spellingShingle |
de Bittencourt, Viviane Conceição Duarte Vicenti, Juliano Rosa de Menezes Velasques, Jecika Maciel Zambiazi, Priscilla Jussiane Gervini, Vanessa Carratu 2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide |
| author_facet |
de Bittencourt, Viviane Conceição Duarte Vicenti, Juliano Rosa de Menezes Velasques, Jecika Maciel Zambiazi, Priscilla Jussiane Gervini, Vanessa Carratu |
| author_sort |
de Bittencourt, Viviane Conceição Duarte |
| title |
2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide |
| title_short |
2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide |
| title_full |
2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide |
| title_fullStr |
2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide |
| title_full_unstemmed |
2-(5-Chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide |
| title_sort |
2-(5-chloro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide |
| description |
The title molecule, C9H7ClN4OS, is almost planar, with an r.m.s. deviation of 0.034 (2) Å for the mean plane through all the non-H atoms. Intramolecular N—H⋯O and N—H⋯N hydrogen bonds form S(6) and S(5) ring motifs, respectively. In the crystal, molecules are assembled into inversion dimers through pairs of co-operative N—H⋯Cl interactions. These dimers are connected along the b axis by N—H⋯O and N—H⋯S hydrogen bonds, generating layers parallel to (103). The layers are further connected along the a axis into a three-dimensional network, through weak π–π stacking interactions [centroid–centroid distance = 3.849 (2) Å]. |
| publisher |
International Union of Crystallography |
| publishDate |
2013 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029216/ |
| _version_ |
1612091589331517440 |