Tri-μ-chlorido-bis­[(η5-penta­methyl­cyclo­penta­dien­yl)rhodium(III)] hexa­fluorido­phosphate from synchrotron radiation

Tri-μ-chlorido-bis­[(η5-penta­methyl­cyclo­penta­dien­yl)rhodium(III)] hexa­fluorido­phosphate from synchrotron radiation

In the title complex salt, [{(η5-C5Me5)Rh}2(μ-Cl)3]PF6, the dinuclear, single-charged cation is formed by the cojoining of two classic (η5-C5Me5)RhCl3 ‘piano-stool’ units by bridging of the three choride ligand ‘legs’. The crystal structure shows several close H⋯F contacts between the hexa­fluorido­...

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Bibliographic Details
Main Authors: Ezzedinloo, Lida, Shrestha, Sumi, Bhadbhade, Mohan, Colbran, Stephen
Format: Online
Language:English
Published: International Union of Crystallography 2013
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029212/

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4029212/

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