(2.2.2-Cryptand)potassium tetracarbonylcobaltate(−I)
The title salt, [K(C18H36N2O6)][Co(CO)4], is an example of a classical carbonylmetalate. The asymmetric unit contains one cation and one tetrahedral anion, both in general positions. Based on comparison of the four carbonyl C—O bond lengths and C—Co—C angles, the anion is unperturbed by the cation,...
Main Authors: | , |
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Format: | Online |
Language: | English |
Published: |
International Union of Crystallography
2014
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Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011216/ |