(2.2.2-Cryptand)potassium tetra­carbonyl­cobaltate(−I)

The title salt, [K(C18H36N2O6)][Co(CO)4], is an example of a classical carbonyl­metalate. The asymmetric unit contains one cation and one tetrahedral anion, both in general positions. Based on comparison of the four carbonyl C—O bond lengths and C—Co—C angles, the anion is unperturbed by the cation,...

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Bibliographic Details
Main Authors: Brennessel, William W., Ellis, John E.
Format: Online
Language:English
Published: International Union of Crystallography 2014
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4011216/