Triphenyltellurium chloride
The asymmetric unit of the title compound, C18H15ClTe, contains two molecules which are in inverted orientations. The compound displays a tetrahedral geometry around the Te atom in spite of there being five electron domains. This is attributed to the fact that the lone pair is not sterically activ...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2014
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998628/ |
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pubmed-3998628 |
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oai_dc |
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pubmed-39986282014-05-13 Triphenyltellurium chloride Chopra, Ambika Jain, Shalini Srivastava, Sanjay K. Gupta, Sushil K. Butcher, Ray J. Organic Papers The asymmetric unit of the title compound, C18H15ClTe, contains two molecules which are in inverted orientations. The compound displays a tetrahedral geometry around the Te atom in spite of there being five electron domains. This is attributed to the fact that the lone pair is not sterically active. The dihedral angles between the three phenyl rings are 76.51 (16)/73.75 (16)/71.06 (17) and 78.60 (17)/77.67 (16)/79.11 (16)° in the two molecules. The crystal packing features eight C—H⋯π interactions. International Union of Crystallography 2014-03-12 /pmc/articles/PMC3998628/ /pubmed/24826133 http://dx.doi.org/10.1107/S160053681400498X Text en © Chopra et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Chopra, Ambika Jain, Shalini Srivastava, Sanjay K. Gupta, Sushil K. Butcher, Ray J. |
| spellingShingle |
Chopra, Ambika Jain, Shalini Srivastava, Sanjay K. Gupta, Sushil K. Butcher, Ray J. Triphenyltellurium chloride |
| author_facet |
Chopra, Ambika Jain, Shalini Srivastava, Sanjay K. Gupta, Sushil K. Butcher, Ray J. |
| author_sort |
Chopra, Ambika |
| title |
Triphenyltellurium chloride |
| title_short |
Triphenyltellurium chloride |
| title_full |
Triphenyltellurium chloride |
| title_fullStr |
Triphenyltellurium chloride |
| title_full_unstemmed |
Triphenyltellurium chloride |
| title_sort |
triphenyltellurium chloride |
| description |
The asymmetric unit of the title compound, C18H15ClTe, contains two molecules which are in inverted orientations. The compound displays a tetrahedral geometry around the Te atom in spite of there being five electron domains. This is attributed to the fact that the lone pair is not sterically active. The dihedral angles between the three phenyl rings are 76.51 (16)/73.75 (16)/71.06 (17) and 78.60 (17)/77.67 (16)/79.11 (16)° in the two molecules. The crystal packing features eight C—H⋯π interactions. |
| publisher |
International Union of Crystallography |
| publishDate |
2014 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998628/ |
| _version_ |
1612082146877374464 |