N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide

N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide

There are two independent mol­ecules in the asymmetric unit of the title compound, C12H15N3S, both of which display disorder of several C atoms in the N-bound ring (occupancy ratios of 0.75:0.25 in the first independent mol­ecule and 0.50:0.50 in the second) with the methyl H atoms also being disord...

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Main Authors: de Oliveira, Adriano Bof, Feitosa, Bárbara Regina Santos, Näther, Christian, Jess, Inke
Format: Online
Language:English
Published: International Union of Crystallography 2014
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998428/
id pubmed-3998428
recordtype oai_dc
spelling pubmed-39984282014-04-24 N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide de Oliveira, Adriano Bof Feitosa, Bárbara Regina Santos Näther, Christian Jess, Inke Organic Papers There are two independent mol­ecules in the asymmetric unit of the title compound, C12H15N3S, both of which display disorder of several C atoms in the N-bound ring (occupancy ratios of 0.75:0.25 in the first independent mol­ecule and 0.50:0.50 in the second) with the methyl H atoms also being disordered in the first mol­ecule (occupancy ratio of 0.70:0.30). The planes of the benzene ring and the N—N—C—N fragment make dihedral angles of 12.92 (14)° in the first independent mol­ecule and 7.60 (13)° in the second. In the crystal, mol­ecules are linked by weak N—H⋯S hydrogen bonds into chains along the a-axis direction. The crystal packing ressembles a herringbone arrangement. International Union of Crystallography 2014-02-15 /pmc/articles/PMC3998428/ /pubmed/24765005 http://dx.doi.org/10.1107/S1600536814003079 Text en © Oliveira et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
repository_type Open Access Journal
institution_category Foreign Institution
institution US National Center for Biotechnology Information
building NCBI PubMed
collection Online Access
language English
format Online
author de Oliveira, Adriano Bof
Feitosa, Bárbara Regina Santos
Näther, Christian
Jess, Inke
spellingShingle de Oliveira, Adriano Bof
Feitosa, Bárbara Regina Santos
Näther, Christian
Jess, Inke
N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide
author_facet de Oliveira, Adriano Bof
Feitosa, Bárbara Regina Santos
Näther, Christian
Jess, Inke
author_sort de Oliveira, Adriano Bof
title N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide
title_short N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide
title_full N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide
title_fullStr N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide
title_full_unstemmed N-Methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide
title_sort n-methyl-2-(1,2,3,4-tetra­hydro­naph­thalen-1-yl­idene)hydrazinecarbo­thio­amide
description There are two independent mol­ecules in the asymmetric unit of the title compound, C12H15N3S, both of which display disorder of several C atoms in the N-bound ring (occupancy ratios of 0.75:0.25 in the first independent mol­ecule and 0.50:0.50 in the second) with the methyl H atoms also being disordered in the first mol­ecule (occupancy ratio of 0.70:0.30). The planes of the benzene ring and the N—N—C—N fragment make dihedral angles of 12.92 (14)° in the first independent mol­ecule and 7.60 (13)° in the second. In the crystal, mol­ecules are linked by weak N—H⋯S hydrogen bonds into chains along the a-axis direction. The crystal packing ressembles a herringbone arrangement.
publisher International Union of Crystallography
publishDate 2014
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998428/
_version_ 1612082035762921472

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