2-(4-Chlorophenyl)-2,3-dihydroquinolin-4(1H)-one
The title molecule, C15H12ClNO, features a dihydroquinolin-4(1H)-one moiety attached to a chlorobenzene ring. The heterocyclic ring has a half-chair conformation with the methine C atom lying 0.574 (3) Å above the plane of the five remaining atoms (r.m.s. deviation = 0.0240 Å). The dihedral angl...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2014
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998350/ |
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pubmed-3998350 |
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oai_dc |
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pubmed-39983502014-04-24 2-(4-Chlorophenyl)-2,3-dihydroquinolin-4(1H)-one Chelghoum, Meryem Bouraiou, Abdelmalek Bouacida, Sofiane Bahnous, Mebarek Belfaitah, Ali Organic Papers The title molecule, C15H12ClNO, features a dihydroquinolin-4(1H)-one moiety attached to a chlorobenzene ring. The heterocyclic ring has a half-chair conformation with the methine C atom lying 0.574 (3) Å above the plane of the five remaining atoms (r.m.s. deviation = 0.0240 Å). The dihedral angles between the terminal benzene rings is 77.53 (9)°, indicating a significant twist in the molecule. In the crystal, supramolecular zigzag chains along the c-axis direction are sustained by N—H⋯O hydrogen bonds. These are connected into double chains by C—H⋯π interactions. International Union of Crystallography 2014-01-25 /pmc/articles/PMC3998350/ /pubmed/24764911 http://dx.doi.org/10.1107/S1600536814001548 Text en © Chelghoum et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Chelghoum, Meryem Bouraiou, Abdelmalek Bouacida, Sofiane Bahnous, Mebarek Belfaitah, Ali |
| spellingShingle |
Chelghoum, Meryem Bouraiou, Abdelmalek Bouacida, Sofiane Bahnous, Mebarek Belfaitah, Ali 2-(4-Chlorophenyl)-2,3-dihydroquinolin-4(1H)-one |
| author_facet |
Chelghoum, Meryem Bouraiou, Abdelmalek Bouacida, Sofiane Bahnous, Mebarek Belfaitah, Ali |
| author_sort |
Chelghoum, Meryem |
| title |
2-(4-Chlorophenyl)-2,3-dihydroquinolin-4(1H)-one |
| title_short |
2-(4-Chlorophenyl)-2,3-dihydroquinolin-4(1H)-one |
| title_full |
2-(4-Chlorophenyl)-2,3-dihydroquinolin-4(1H)-one |
| title_fullStr |
2-(4-Chlorophenyl)-2,3-dihydroquinolin-4(1H)-one |
| title_full_unstemmed |
2-(4-Chlorophenyl)-2,3-dihydroquinolin-4(1H)-one |
| title_sort |
2-(4-chlorophenyl)-2,3-dihydroquinolin-4(1h)-one |
| description |
The title molecule, C15H12ClNO, features a dihydroquinolin-4(1H)-one moiety attached to a chlorobenzene ring. The heterocyclic ring has a half-chair conformation with the methine C atom lying 0.574 (3) Å above the plane of the five remaining atoms (r.m.s. deviation = 0.0240 Å). The dihedral angles between the terminal benzene rings is 77.53 (9)°, indicating a significant twist in the molecule. In the crystal, supramolecular zigzag chains along the c-axis direction are sustained by N—H⋯O hydrogen bonds. These are connected into double chains by C—H⋯π interactions. |
| publisher |
International Union of Crystallography |
| publishDate |
2014 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998350/ |
| _version_ |
1612081995867750400 |