Bis(hydroxyammonium) hexachloridoplatinate(IV)–18-crown-6 (1/2)
In the title complex, (NH3OH)2[PtCl6]·2C12H24O6, the PtIV atom is coordinated by six chloride anions in a slightly distorted octahedral geometry. The Pt—Cl bond lengths are comparable to those reported for other hexachloridoplatinate(IV) species. The hydroxyammonium groups act as linkers betwee...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2013
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914042/ |
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pubmed-3914042 |
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pubmed-39140422014-02-13 Bis(hydroxyammonium) hexachloridoplatinate(IV)–18-crown-6 (1/2) Bulatov, Evgeny Afanasenko, Anastasiya Chulkova, Tatiana Haukka, Matti Metal-Organic Papers In the title complex, (NH3OH)2[PtCl6]·2C12H24O6, the PtIV atom is coordinated by six chloride anions in a slightly distorted octahedral geometry. The Pt—Cl bond lengths are comparable to those reported for other hexachloridoplatinate(IV) species. The hydroxyammonium groups act as linkers between the [PtCl6]2− anion and the crown ether molecules. The anion is linked to two hydroxyammonium cations via O—H⋯Cl hydrogen bonds and each hydroxyammonium moiety is linked to a crown ether molecule by hydrogen bonds between ammonium H atoms and 18-crown-6 O atoms. The crown ether molecules have the classic crown shape in which all O atoms are located in the inner part of the crown ether ring and all –CH2– groups are turned to the outside. International Union of Crystallography 2013-12-07 /pmc/articles/PMC3914042/ /pubmed/24526958 http://dx.doi.org/10.1107/S1600536813032649 Text en © Bulatov et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Bulatov, Evgeny Afanasenko, Anastasiya Chulkova, Tatiana Haukka, Matti |
| spellingShingle |
Bulatov, Evgeny Afanasenko, Anastasiya Chulkova, Tatiana Haukka, Matti Bis(hydroxyammonium) hexachloridoplatinate(IV)–18-crown-6 (1/2) |
| author_facet |
Bulatov, Evgeny Afanasenko, Anastasiya Chulkova, Tatiana Haukka, Matti |
| author_sort |
Bulatov, Evgeny |
| title |
Bis(hydroxyammonium) hexachloridoplatinate(IV)–18-crown-6 (1/2) |
| title_short |
Bis(hydroxyammonium) hexachloridoplatinate(IV)–18-crown-6 (1/2) |
| title_full |
Bis(hydroxyammonium) hexachloridoplatinate(IV)–18-crown-6 (1/2) |
| title_fullStr |
Bis(hydroxyammonium) hexachloridoplatinate(IV)–18-crown-6 (1/2) |
| title_full_unstemmed |
Bis(hydroxyammonium) hexachloridoplatinate(IV)–18-crown-6 (1/2) |
| title_sort |
bis(hydroxyammonium) hexachloridoplatinate(iv)–18-crown-6 (1/2) |
| description |
In the title complex, (NH3OH)2[PtCl6]·2C12H24O6, the PtIV atom is coordinated by six chloride anions in a slightly distorted octahedral geometry. The Pt—Cl bond lengths are comparable to those reported for other hexachloridoplatinate(IV) species. The hydroxyammonium groups act as linkers between the [PtCl6]2− anion and the crown ether molecules. The anion is linked to two hydroxyammonium cations via O—H⋯Cl hydrogen bonds and each hydroxyammonium moiety is linked to a crown ether molecule by hydrogen bonds between ammonium H atoms and 18-crown-6 O atoms. The crown ether molecules have the classic crown shape in which all O atoms are located in the inner part of the crown ether ring and all –CH2– groups are turned to the outside. |
| publisher |
International Union of Crystallography |
| publishDate |
2013 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914042/ |
| _version_ |
1612054908073148416 |