2-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrile
X-ray crystallography firmly established the relative stereochemistry of the title compound, C16H20N2O3. The acetonide ring adopts an envelope conformation with one of the O atoms as the flap and the piperidine ring adopts a slightly twisted boat conformation. The absolute configuration was determin...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2013
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885044/ |
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pubmed-3885044 |
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oai_dc |
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pubmed-38850442014-01-17 2-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrile Ayers, Benjamin J. Jenkinson, Sarah F. Fleet, George W. J. Thompson, Amber L. Organic Papers X-ray crystallography firmly established the relative stereochemistry of the title compound, C16H20N2O3. The acetonide ring adopts an envelope conformation with one of the O atoms as the flap and the piperidine ring adopts a slightly twisted boat conformation. The absolute configuration was determined by use of d-ribose as the starting material. The compound exists as O—H⋯O hydrogen-bonded chains of molecules running parallel to the b axis. International Union of Crystallography 2013-11-13 /pmc/articles/PMC3885044/ /pubmed/24454220 http://dx.doi.org/10.1107/S1600536813030584 Text en © Ayers et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Ayers, Benjamin J. Jenkinson, Sarah F. Fleet, George W. J. Thompson, Amber L. |
| spellingShingle |
Ayers, Benjamin J. Jenkinson, Sarah F. Fleet, George W. J. Thompson, Amber L. 2-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrile |
| author_facet |
Ayers, Benjamin J. Jenkinson, Sarah F. Fleet, George W. J. Thompson, Amber L. |
| author_sort |
Ayers, Benjamin J. |
| title |
2-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrile |
| title_short |
2-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrile |
| title_full |
2-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrile |
| title_fullStr |
2-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrile |
| title_full_unstemmed |
2-N-Benzyl-2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-d-allononitrile |
| title_sort |
2-n-benzyl-2,6-dideoxy-2,6-imino-3,4-o-isopropylidene-d-allononitrile |
| description |
X-ray crystallography firmly established the relative stereochemistry of the title compound, C16H20N2O3. The acetonide ring adopts an envelope conformation with one of the O atoms as the flap and the piperidine ring adopts a slightly twisted boat conformation. The absolute configuration was determined by use of d-ribose as the starting material. The compound exists as O—H⋯O hydrogen-bonded chains of molecules running parallel to the b axis. |
| publisher |
International Union of Crystallography |
| publishDate |
2013 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885044/ |
| _version_ |
1612045620164427776 |