exo-1,7-Dimethyl-4-phenyl-10-oxa-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione
The title compound, C16H15NO3, consists of an oxabicycle fused to an N-phenyl-substituted pyrrolidine ring anti to the double bond, affording the exo isomer. In the oxabicycle system, the six-membered ring presents a boat conformation, while the heterocyclic rings show envelope conformations with th...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2013
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885034/ |
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pubmed-3885034 |
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oai_dc |
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pubmed-38850342014-01-17 exo-1,7-Dimethyl-4-phenyl-10-oxa-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione Pineda-Contreras, Armando Vázquez-Vuelvas, Oscar Fernando Negrete-López, Laura Edith García-Ortega, Héctor Flores-Alamo, Marcos Organic Papers The title compound, C16H15NO3, consists of an oxabicycle fused to an N-phenyl-substituted pyrrolidine ring anti to the double bond, affording the exo isomer. In the oxabicycle system, the six-membered ring presents a boat conformation, while the heterocyclic rings show envelope conformations with the O atom projected out of the plane. In the crystal, adjacent molecules are linked via weak C—H⋯O hydrogen bonds, forming chains propagating along the a-axis direction. The chains are linked by C—H⋯π interactions, forming two-dimensional networks lying parallel to the ac plane. International Union of Crystallography 2013-11-09 /pmc/articles/PMC3885034/ /pubmed/24454209 http://dx.doi.org/10.1107/S1600536813030262 Text en © Pineda-Contreras et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Pineda-Contreras, Armando Vázquez-Vuelvas, Oscar Fernando Negrete-López, Laura Edith García-Ortega, Héctor Flores-Alamo, Marcos |
| spellingShingle |
Pineda-Contreras, Armando Vázquez-Vuelvas, Oscar Fernando Negrete-López, Laura Edith García-Ortega, Héctor Flores-Alamo, Marcos exo-1,7-Dimethyl-4-phenyl-10-oxa-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione |
| author_facet |
Pineda-Contreras, Armando Vázquez-Vuelvas, Oscar Fernando Negrete-López, Laura Edith García-Ortega, Héctor Flores-Alamo, Marcos |
| author_sort |
Pineda-Contreras, Armando |
| title |
exo-1,7-Dimethyl-4-phenyl-10-oxa-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione |
| title_short |
exo-1,7-Dimethyl-4-phenyl-10-oxa-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione |
| title_full |
exo-1,7-Dimethyl-4-phenyl-10-oxa-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione |
| title_fullStr |
exo-1,7-Dimethyl-4-phenyl-10-oxa-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione |
| title_full_unstemmed |
exo-1,7-Dimethyl-4-phenyl-10-oxa-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione |
| title_sort |
exo-1,7-dimethyl-4-phenyl-10-oxa-4-azatricyclo[5.2.1.02,6]dec-8-ene-3,5-dione |
| description |
The title compound, C16H15NO3, consists of an oxabicycle fused to an N-phenyl-substituted pyrrolidine ring anti to the double bond, affording the exo isomer. In the oxabicycle system, the six-membered ring presents a boat conformation, while the heterocyclic rings show envelope conformations with the O atom projected out of the plane. In the crystal, adjacent molecules are linked via weak C—H⋯O hydrogen bonds, forming chains propagating along the a-axis direction. The chains are linked by C—H⋯π interactions, forming two-dimensional networks lying parallel to the ac plane. |
| publisher |
International Union of Crystallography |
| publishDate |
2013 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885034/ |
| _version_ |
1612045614676180992 |