1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II)

1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II)

In the title salt, (C12H20N2)[CuCl4], the CuII atom occupies a general position in a flattened tetra­hedral environment by Cl ligands, characterized by Cl—Cu—Cl angles of 134.04 (3) and 137.18 (4)°. The six-membered piperazinediium ring adopts a chair conformation. The organic cation and inorganic a...

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Main Authors: Ben Mabrouk, Safa, Ameur, Iness, Abid, Sonia, Rzaigui, Mohamed
Format: Online
Language:English
Published: International Union of Crystallography 2013
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884381/
id pubmed-3884381
recordtype oai_dc
spelling pubmed-38843812014-01-14 1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II) Ben Mabrouk, Safa Ameur, Iness Abid, Sonia Rzaigui, Mohamed Metal-Organic Papers In the title salt, (C12H20N2)[CuCl4], the CuII atom occupies a general position in a flattened tetra­hedral environment by Cl ligands, characterized by Cl—Cu—Cl angles of 134.04 (3) and 137.18 (4)°. The six-membered piperazinediium ring adopts a chair conformation. The organic cation and inorganic anion inter­act through N—H⋯Cl and C—H⋯Cl hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2013-08-10 /pmc/articles/PMC3884381/ /pubmed/24426985 http://dx.doi.org/10.1107/S1600536813021454 Text en © Ben Mabrouk et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
repository_type Open Access Journal
institution_category Foreign Institution
institution US National Center for Biotechnology Information
building NCBI PubMed
collection Online Access
language English
format Online
author Ben Mabrouk, Safa
Ameur, Iness
Abid, Sonia
Rzaigui, Mohamed
spellingShingle Ben Mabrouk, Safa
Ameur, Iness
Abid, Sonia
Rzaigui, Mohamed
1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II)
author_facet Ben Mabrouk, Safa
Ameur, Iness
Abid, Sonia
Rzaigui, Mohamed
author_sort Ben Mabrouk, Safa
title 1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II)
title_short 1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II)
title_full 1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II)
title_fullStr 1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II)
title_full_unstemmed 1-(2,3-Di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(II)
title_sort 1-(2,3-di­methyl­phen­yl)piperazine-1,4-diium tetra­chlorido­cuprate(ii)
description In the title salt, (C12H20N2)[CuCl4], the CuII atom occupies a general position in a flattened tetra­hedral environment by Cl ligands, characterized by Cl—Cu—Cl angles of 134.04 (3) and 137.18 (4)°. The six-membered piperazinediium ring adopts a chair conformation. The organic cation and inorganic anion inter­act through N—H⋯Cl and C—H⋯Cl hydrogen bonds, forming a three-dimensional network.
publisher International Union of Crystallography
publishDate 2013
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884381/
_version_ 1612045342388256768

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