2-[1-(2-Hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amide

In the title compound, C11H15N3O2S, the dihedral angle between the mean planes of the benzene ring and hydrazinecarbo­thio­amide group is 9.2 (1)°. An intra­molecular O—H⋯N hydrogen bond is observed, serving to maintain an approximately planar conformation for the molecule. In the crystal, inversion...

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Main Authors: Anderson, Brian J., Freedman, Michael B., Millikan, Sean P., Jasinski, Jerry P.
Format: Online
Language:English
Published: International Union of Crystallography 2013
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793802/
id pubmed-3793802
recordtype oai_dc
spelling pubmed-37938022013-10-09 2-[1-(2-Hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amide Anderson, Brian J. Freedman, Michael B. Millikan, Sean P. Jasinski, Jerry P. Organic Papers In the title compound, C11H15N3O2S, the dihedral angle between the mean planes of the benzene ring and hydrazinecarbo­thio­amide group is 9.2 (1)°. An intra­molecular O—H⋯N hydrogen bond is observed, serving to maintain an approximately planar conformation for the molecule. In the crystal, inversion dimers linked by C—H⋯O inter­actions occur. Further C—H⋯O contacts link dimers into (010) chains. International Union of Crystallography 2013-07-24 /pmc/articles/PMC3793802/ /pubmed/24109389 http://dx.doi.org/10.1107/S1600536813019831 Text en © Anderson et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
repository_type Open Access Journal
institution_category Foreign Institution
institution US National Center for Biotechnology Information
building NCBI PubMed
collection Online Access
language English
format Online
author Anderson, Brian J.
Freedman, Michael B.
Millikan, Sean P.
Jasinski, Jerry P.
spellingShingle Anderson, Brian J.
Freedman, Michael B.
Millikan, Sean P.
Jasinski, Jerry P.
2-[1-(2-Hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amide
author_facet Anderson, Brian J.
Freedman, Michael B.
Millikan, Sean P.
Jasinski, Jerry P.
author_sort Anderson, Brian J.
title 2-[1-(2-Hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amide
title_short 2-[1-(2-Hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amide
title_full 2-[1-(2-Hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amide
title_fullStr 2-[1-(2-Hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amide
title_full_unstemmed 2-[1-(2-Hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-N-methyl­hydrazinecarbo­thio­amide
title_sort 2-[1-(2-hy­droxy-4-meth­oxy­phen­yl)ethyl­idene]-n-methyl­hydrazinecarbo­thio­amide
description In the title compound, C11H15N3O2S, the dihedral angle between the mean planes of the benzene ring and hydrazinecarbo­thio­amide group is 9.2 (1)°. An intra­molecular O—H⋯N hydrogen bond is observed, serving to maintain an approximately planar conformation for the molecule. In the crystal, inversion dimers linked by C—H⋯O inter­actions occur. Further C—H⋯O contacts link dimers into (010) chains.
publisher International Union of Crystallography
publishDate 2013
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793802/
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