1,10,10-Trimethyl-5-phenyl-3-oxa-4-azatricyclo[5.2.1.02,6]dec-4-en-2-ol
The title compound, C17H21NO2, was synthesized by the reaction of (1R)-(+)-3-benzylcamphor and hydroxylamine. The oxazole ring makes a dihedral angle of 23.42 (16)° with the phenyl ring. The six-membered ring of the norboryl group adopts a boat conformation, whereas each of the five-membered rings...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2013
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793801/ |
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pubmed-3793801 |
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oai_dc |
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pubmed-37938012013-10-09 1,10,10-Trimethyl-5-phenyl-3-oxa-4-azatricyclo[5.2.1.02,6]dec-4-en-2-ol Boualy, Brahim Harrad, Mohamed Anouar Oudahmane, Abdelghani Benharref, Ahmed Berraho, Moha Organic Papers The title compound, C17H21NO2, was synthesized by the reaction of (1R)-(+)-3-benzylcamphor and hydroxylamine. The oxazole ring makes a dihedral angle of 23.42 (16)° with the phenyl ring. The six-membered ring of the norboryl group adopts a boat conformation, whereas each of the five-membered rings of the norboryl group displays a flattened envelope conformation, with the C atom carrying the methyl groups representing the flap for both rings. In the crystal, molecules are linked into zigzag chains propagating along the b axis by O—H⋯N hydrogen bonds. International Union of Crystallography 2013-07-24 /pmc/articles/PMC3793801/ /pubmed/24109388 http://dx.doi.org/10.1107/S160053681302000X Text en © Boualy et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Boualy, Brahim Harrad, Mohamed Anouar Oudahmane, Abdelghani Benharref, Ahmed Berraho, Moha |
| spellingShingle |
Boualy, Brahim Harrad, Mohamed Anouar Oudahmane, Abdelghani Benharref, Ahmed Berraho, Moha 1,10,10-Trimethyl-5-phenyl-3-oxa-4-azatricyclo[5.2.1.02,6]dec-4-en-2-ol |
| author_facet |
Boualy, Brahim Harrad, Mohamed Anouar Oudahmane, Abdelghani Benharref, Ahmed Berraho, Moha |
| author_sort |
Boualy, Brahim |
| title |
1,10,10-Trimethyl-5-phenyl-3-oxa-4-azatricyclo[5.2.1.02,6]dec-4-en-2-ol |
| title_short |
1,10,10-Trimethyl-5-phenyl-3-oxa-4-azatricyclo[5.2.1.02,6]dec-4-en-2-ol |
| title_full |
1,10,10-Trimethyl-5-phenyl-3-oxa-4-azatricyclo[5.2.1.02,6]dec-4-en-2-ol |
| title_fullStr |
1,10,10-Trimethyl-5-phenyl-3-oxa-4-azatricyclo[5.2.1.02,6]dec-4-en-2-ol |
| title_full_unstemmed |
1,10,10-Trimethyl-5-phenyl-3-oxa-4-azatricyclo[5.2.1.02,6]dec-4-en-2-ol |
| title_sort |
1,10,10-trimethyl-5-phenyl-3-oxa-4-azatricyclo[5.2.1.02,6]dec-4-en-2-ol |
| description |
The title compound, C17H21NO2, was synthesized by the reaction of (1R)-(+)-3-benzylcamphor and hydroxylamine. The oxazole ring makes a dihedral angle of 23.42 (16)° with the phenyl ring. The six-membered ring of the norboryl group adopts a boat conformation, whereas each of the five-membered rings of the norboryl group displays a flattened envelope conformation, with the C atom carrying the methyl groups representing the flap for both rings. In the crystal, molecules are linked into zigzag chains propagating along the b axis by O—H⋯N hydrogen bonds. |
| publisher |
International Union of Crystallography |
| publishDate |
2013 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793801/ |
| _version_ |
1612017355896913920 |