2-(10′,10′-Dimethyl-3′-sulfanylidene-4′-azatricyclo[5.2.1.01,5]decan-2′-yl)-10,10-dimethyl-4-azatricyclo[5.2.1.01,5]decane-3-thione
The title compound, C28H40N2O2S2, was obtained as a minor product from an anti-aldol reaction between the corresponding N-propionylthiolactam and benzaldehyde. The asymmetric unit contains one half-molecule, which is completed by inversion symmetry. The molecule displays a nearly eclipsed conforma...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2013
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793777/ |
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pubmed-3793777 |
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oai_dc |
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pubmed-37937772013-10-09 2-(10′,10′-Dimethyl-3′-sulfanylidene-4′-azatricyclo[5.2.1.01,5]decan-2′-yl)-10,10-dimethyl-4-azatricyclo[5.2.1.01,5]decane-3-thione Walker, Ashley Forsyth, Craig M. Perlmutter, Patrick Organic Papers The title compound, C28H40N2O2S2, was obtained as a minor product from an anti-aldol reaction between the corresponding N-propionylthiolactam and benzaldehyde. The asymmetric unit contains one half-molecule, which is completed by inversion symmetry. The molecule displays a nearly eclipsed conformation along the central C—C bond with a C—C—C—C— torsion angle of 20.4 (3)°. International Union of Crystallography 2013-07-20 /pmc/articles/PMC3793777/ /pubmed/24109364 http://dx.doi.org/10.1107/S1600536813019211 Text en © Walker et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Walker, Ashley Forsyth, Craig M. Perlmutter, Patrick |
| spellingShingle |
Walker, Ashley Forsyth, Craig M. Perlmutter, Patrick 2-(10′,10′-Dimethyl-3′-sulfanylidene-4′-azatricyclo[5.2.1.01,5]decan-2′-yl)-10,10-dimethyl-4-azatricyclo[5.2.1.01,5]decane-3-thione |
| author_facet |
Walker, Ashley Forsyth, Craig M. Perlmutter, Patrick |
| author_sort |
Walker, Ashley |
| title |
2-(10′,10′-Dimethyl-3′-sulfanylidene-4′-azatricyclo[5.2.1.01,5]decan-2′-yl)-10,10-dimethyl-4-azatricyclo[5.2.1.01,5]decane-3-thione |
| title_short |
2-(10′,10′-Dimethyl-3′-sulfanylidene-4′-azatricyclo[5.2.1.01,5]decan-2′-yl)-10,10-dimethyl-4-azatricyclo[5.2.1.01,5]decane-3-thione |
| title_full |
2-(10′,10′-Dimethyl-3′-sulfanylidene-4′-azatricyclo[5.2.1.01,5]decan-2′-yl)-10,10-dimethyl-4-azatricyclo[5.2.1.01,5]decane-3-thione |
| title_fullStr |
2-(10′,10′-Dimethyl-3′-sulfanylidene-4′-azatricyclo[5.2.1.01,5]decan-2′-yl)-10,10-dimethyl-4-azatricyclo[5.2.1.01,5]decane-3-thione |
| title_full_unstemmed |
2-(10′,10′-Dimethyl-3′-sulfanylidene-4′-azatricyclo[5.2.1.01,5]decan-2′-yl)-10,10-dimethyl-4-azatricyclo[5.2.1.01,5]decane-3-thione |
| title_sort |
2-(10′,10′-dimethyl-3′-sulfanylidene-4′-azatricyclo[5.2.1.01,5]decan-2′-yl)-10,10-dimethyl-4-azatricyclo[5.2.1.01,5]decane-3-thione |
| description |
The title compound, C28H40N2O2S2, was obtained as a minor product from an anti-aldol reaction between the corresponding N-propionylthiolactam and benzaldehyde. The asymmetric unit contains one half-molecule, which is completed by inversion symmetry. The molecule displays a nearly eclipsed conformation along the central C—C bond with a C—C—C—C— torsion angle of 20.4 (3)°. |
| publisher |
International Union of Crystallography |
| publishDate |
2013 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793777/ |
| _version_ |
1612017342101848064 |