Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed annulation with diarylethynes

Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed annulation with diarylethynes

When Boc-L-Val-OH was used as a ligand for the enantioselective Pd(II)-catalyzed annulation of N,N-substituted aminomethyl ferrocene derivatives with diarylethynes, ferrocenes with planar chirality could be achieved with excellent enantioselectivity (up to 99% ee).

Bibliographic Details
Main Authors: Shi, Yan-Chao, Yang, Rong-Fei, Gao, De-Wei, You, Shu-Li
Format: Online
Language:English
Published: Beilstein-Institut 2013
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3778326/
id pubmed-3778326
recordtype oai_dc
spelling pubmed-37783262013-09-23 Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed annulation with diarylethynes Shi, Yan-Chao Yang, Rong-Fei Gao, De-Wei You, Shu-Li Letter When Boc-L-Val-OH was used as a ligand for the enantioselective Pd(II)-catalyzed annulation of N,N-substituted aminomethyl ferrocene derivatives with diarylethynes, ferrocenes with planar chirality could be achieved with excellent enantioselectivity (up to 99% ee). Beilstein-Institut 2013-09-18 /pmc/articles/PMC3778326/ /pubmed/24062858 http://dx.doi.org/10.3762/bjoc.9.222 Text en Copyright © 2013, Shi et al; licensee Beilstein-Institut. http://www.beilstein-journals.org/bjoc This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc)
repository_type Open Access Journal
institution_category Foreign Institution
institution US National Center for Biotechnology Information
building NCBI PubMed
collection Online Access
language English
format Online
author Shi, Yan-Chao
Yang, Rong-Fei
Gao, De-Wei
You, Shu-Li
spellingShingle Shi, Yan-Chao
Yang, Rong-Fei
Gao, De-Wei
You, Shu-Li
Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed annulation with diarylethynes
author_facet Shi, Yan-Chao
Yang, Rong-Fei
Gao, De-Wei
You, Shu-Li
author_sort Shi, Yan-Chao
title Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed annulation with diarylethynes
title_short Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed annulation with diarylethynes
title_full Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed annulation with diarylethynes
title_fullStr Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed annulation with diarylethynes
title_full_unstemmed Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed annulation with diarylethynes
title_sort enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed annulation with diarylethynes
description When Boc-L-Val-OH was used as a ligand for the enantioselective Pd(II)-catalyzed annulation of N,N-substituted aminomethyl ferrocene derivatives with diarylethynes, ferrocenes with planar chirality could be achieved with excellent enantioselectivity (up to 99% ee).
publisher Beilstein-Institut
publishDate 2013
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3778326/
_version_ 1612013034677469184

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