Dioximate- and Bis(salicylaldiminate)-Bridged Titanium and Zirconium Alkoxides: Structure Elucidation by Mass Spectrometry

The treatment of titanium alkoxides with 1,5-pentanedioxime or 2,5-hexanedioxime resulted in the formation of complexes [{TiL(OR)2}2] in which the dioximate ligands (L) bridge a dimeric Ti2(μ2-OR)2 unit. The structures of the complexes were determined by single-crystal structure analysis, ESI mass s...

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Bibliographic Details
Main Authors: Maurer, Christian, Pittenauer, Ernst, Puchberger, Michael, Allmaier, Günter, Schubert, Ulrich
Format: Online
Language:English
Published: WILEY-VCH Verlag 2013
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3688322/