3,4-Bis[1-(prop-2-yn­yl)-1H-indol-3-yl]-1H-pyrrole-2,5-dione

In the title mol­ecule, C26H17N3O2, both indole ring systems are essentially planar, with maximum deviations of 0.019 (2) and 0.033 (1) Å for the N atoms, and form dihedral angles of 34.40 (9) and 45.06 (8)° with the essentially planar pyrrole ring [maximum deviation = 0.020 (2) Å]. The dihedral ang...

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Bibliographic Details
Main Authors: Huang, Mu-Hua, Gao, Yong-Chen, Yang, Feng-Ling, Luo, Yun-Jun
Format: Online
Language:English
Published: International Union of Crystallography 2013
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3685074/
Description
Summary:In the title mol­ecule, C26H17N3O2, both indole ring systems are essentially planar, with maximum deviations of 0.019 (2) and 0.033 (1) Å for the N atoms, and form dihedral angles of 34.40 (9) and 45.06 (8)° with the essentially planar pyrrole ring [maximum deviation = 0.020 (2) Å]. The dihedral angle between the two indole ring systems is 58.78 (6)°. In the crystal, mol­ecules are connected by pairs of N—H⋯O hydrogen bonds, forming inversion dimers and generating R 2 2(8) rings. Weak π–π stacking inter­actions, with a centroid–centroid distance of 3.983 (2) Å, are also observed.