Asymmetric Diels–Alder reaction with >C=P– functionality of the 2-phosphaindolizine-η1-P-aluminium(O-menthoxy) dichloride complex: experimental and theoretical results

Asymmetric Diels–Alder reaction with >C=P– functionality of the 2-phosphaindolizine-η1-P-aluminium(O-menthoxy) dichloride complex: experimental and theoretical results

The Diels–Alder reaction of the 2-phosphaindolizine-η1-P-aluminium(O-menthoxy) dichloride complex with dimethylbutadiene was investigated experimentally and computationally. The >C=P– functionality of the complex reacts with 2,3-dimethylbutadiene with complete diastereoselectivity to afford [2 +...

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Bibliographic Details
Main Authors: Jangid, Rajendra K, Sogani, Nidhi, Gupta, Neelima, Bansal, Raj Kumar, von Hopffgarten, Moritz, Frenking, Gernot
Format: Online
Language:English
Published: Beilstein-Institut 2013
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3596042/

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https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3596042/

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