catena-Poly[[[aqua(2,2′-bipyridine-κ2 N,N′)zinc]-μ-furan-2,5-dicarboxylato-κ2 O 2:O 5] dihydrate]
In the title hydrated coordination polymer, {[Zn(C6H2O5)(C10H8N2)(H2O)]·2H2O}n, an infinite [1-10] chain is formed by the linking of [Zn(C10H8N2)(H2O)]2+ entities by bridging, monodentate furan-2,5-dicarboxylate dianionic linkers. The Zn2+ coordination geometry is a trigonal bipyramid, with one N a...
| Main Authors: | , , , , |
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2012
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588728/ |
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pubmed-3588728 |
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| recordtype |
oai_dc |
| spelling |
pubmed-35887282013-03-06 catena-Poly[[[aqua(2,2′-bipyridine-κ2 N,N′)zinc]-μ-furan-2,5-dicarboxylato-κ2 O 2:O 5] dihydrate] Li, Ya-Feng Xu, Yue Qin, Xiao-Lin Yuan, Yong-Peng Gao, Wen-Yuan Metal-Organic Papers In the title hydrated coordination polymer, {[Zn(C6H2O5)(C10H8N2)(H2O)]·2H2O}n, an infinite [1-10] chain is formed by the linking of [Zn(C10H8N2)(H2O)]2+ entities by bridging, monodentate furan-2,5-dicarboxylate dianionic linkers. The Zn2+ coordination geometry is a trigonal bipyramid, with one N atom (from 2,2′-bipyridine) and one O atom (from the bridging dianion) in the axial positions. For each ZnII atom, the dihedral angle between the furan ring of its coordinated bridging ligand and its coordinated bipyridine ring system is 87.19 (8)°. O—H⋯O hydrogen bonds involving both the coordinated and uncoordinated water molecules generate a layer motif parallel to (001). International Union of Crystallography 2012-11-10 /pmc/articles/PMC3588728/ /pubmed/23468693 http://dx.doi.org/10.1107/S1600536812045503 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Li, Ya-Feng Xu, Yue Qin, Xiao-Lin Yuan, Yong-Peng Gao, Wen-Yuan |
| spellingShingle |
Li, Ya-Feng Xu, Yue Qin, Xiao-Lin Yuan, Yong-Peng Gao, Wen-Yuan catena-Poly[[[aqua(2,2′-bipyridine-κ2 N,N′)zinc]-μ-furan-2,5-dicarboxylato-κ2 O 2:O 5] dihydrate] |
| author_facet |
Li, Ya-Feng Xu, Yue Qin, Xiao-Lin Yuan, Yong-Peng Gao, Wen-Yuan |
| author_sort |
Li, Ya-Feng |
| title |
catena-Poly[[[aqua(2,2′-bipyridine-κ2
N,N′)zinc]-μ-furan-2,5-dicarboxylato-κ2
O
2:O
5] dihydrate] |
| title_short |
catena-Poly[[[aqua(2,2′-bipyridine-κ2
N,N′)zinc]-μ-furan-2,5-dicarboxylato-κ2
O
2:O
5] dihydrate] |
| title_full |
catena-Poly[[[aqua(2,2′-bipyridine-κ2
N,N′)zinc]-μ-furan-2,5-dicarboxylato-κ2
O
2:O
5] dihydrate] |
| title_fullStr |
catena-Poly[[[aqua(2,2′-bipyridine-κ2
N,N′)zinc]-μ-furan-2,5-dicarboxylato-κ2
O
2:O
5] dihydrate] |
| title_full_unstemmed |
catena-Poly[[[aqua(2,2′-bipyridine-κ2
N,N′)zinc]-μ-furan-2,5-dicarboxylato-κ2
O
2:O
5] dihydrate] |
| title_sort |
catena-poly[[[aqua(2,2′-bipyridine-κ2
n,n′)zinc]-μ-furan-2,5-dicarboxylato-κ2
o
2:o
5] dihydrate] |
| description |
In the title hydrated coordination polymer, {[Zn(C6H2O5)(C10H8N2)(H2O)]·2H2O}n, an infinite [1-10] chain is formed by the linking of [Zn(C10H8N2)(H2O)]2+ entities by bridging, monodentate furan-2,5-dicarboxylate dianionic linkers. The Zn2+ coordination geometry is a trigonal bipyramid, with one N atom (from 2,2′-bipyridine) and one O atom (from the bridging dianion) in the axial positions. For each ZnII atom, the dihedral angle between the furan ring of its coordinated bridging ligand and its coordinated bipyridine ring system is 87.19 (8)°. O—H⋯O hydrogen bonds involving both the coordinated and uncoordinated water molecules generate a layer motif parallel to (001). |
| publisher |
International Union of Crystallography |
| publishDate |
2012 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588728/ |
| _version_ |
1611959680928579584 |