Poly[(μ4-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ4-nitrato)dilithium]

Poly[(μ4-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ4-nitrato)dilithium]

In the title compound, [Li2(C6H3N2O4)2(NO3)]n, the two symmetry-independent LiI ions are each in a trigonal–bipyramidal coordination and are bridged by N,O-bonding ligands, forming mol­ecular ribbons propagating in [010]. Each LiI ion is also coordinated by two O atoms from nitrate ions, connecting...

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Main Authors: Starosta, Wojciech, Leciejewicz, Janusz
Format: Online
Language:English
Published: International Union of Crystallography 2012
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588327/
id pubmed-3588327
recordtype oai_dc
spelling pubmed-35883272013-03-08 Poly[(μ4-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ4-nitrato)dilithium] Starosta, Wojciech Leciejewicz, Janusz Metal-Organic Papers In the title compound, [Li2(C6H3N2O4)2(NO3)]n, the two symmetry-independent LiI ions are each in a trigonal–bipyramidal coordination and are bridged by N,O-bonding ligands, forming mol­ecular ribbons propagating in [010]. Each LiI ion is also coordinated by two O atoms from nitrate ions, connecting the ribbons into a three-dimensional network. Very strong intra­molecular O—H⋯O hydrogen bonds occur between the carboxyl and the carboxylate group. International Union of Crystallography 2012-12-19 /pmc/articles/PMC3588327/ /pubmed/23476354 http://dx.doi.org/10.1107/S1600536812050738 Text en © Starosta and Leciejewicz 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
repository_type Open Access Journal
institution_category Foreign Institution
institution US National Center for Biotechnology Information
building NCBI PubMed
collection Online Access
language English
format Online
author Starosta, Wojciech
Leciejewicz, Janusz
spellingShingle Starosta, Wojciech
Leciejewicz, Janusz
Poly[(μ4-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ4-nitrato)dilithium]
author_facet Starosta, Wojciech
Leciejewicz, Janusz
author_sort Starosta, Wojciech
title Poly[(μ4-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ4-nitrato)dilithium]
title_short Poly[(μ4-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ4-nitrato)dilithium]
title_full Poly[(μ4-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ4-nitrato)dilithium]
title_fullStr Poly[(μ4-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ4-nitrato)dilithium]
title_full_unstemmed Poly[(μ4-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ4-nitrato)dilithium]
title_sort poly[(μ4-3-carb­oxy­pyrazine-2-carboxyl­ato)(μ4-nitrato)dilithium]
description In the title compound, [Li2(C6H3N2O4)2(NO3)]n, the two symmetry-independent LiI ions are each in a trigonal–bipyramidal coordination and are bridged by N,O-bonding ligands, forming mol­ecular ribbons propagating in [010]. Each LiI ion is also coordinated by two O atoms from nitrate ions, connecting the ribbons into a three-dimensional network. Very strong intra­molecular O—H⋯O hydrogen bonds occur between the carboxyl and the carboxylate group.
publisher International Union of Crystallography
publishDate 2012
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588327/
_version_ 1611959484157001728

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