Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II)

Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II)

The title compound, [Pd(C14H15N2)2], is a square-planar palladium complex composed of two deprotonated pyrrole-2-carbaldimine ligands coordinating a central PdII atom. In the crystal, three crystallographically independent complex mol­ecules are observed, one of which is located in a general positio...

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Main Author: Imhof, Wolfgang
Format: Online
Language:English
Published: International Union of Crystallography 2013
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569194/
id pubmed-3569194
recordtype oai_dc
spelling pubmed-35691942013-02-19 Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II) Imhof, Wolfgang Metal-Organic Papers The title compound, [Pd(C14H15N2)2], is a square-planar palladium complex composed of two deprotonated pyrrole-2-carbaldimine ligands coordinating a central PdII atom. In the crystal, three crystallographically independent complex mol­ecules are observed, one of which is located in a general position, whereas the PdII atoms of the other mol­ecules are situated on crystallographic inversion centers. The aromatic substituents at the imine N atoms in the three mol­ecules show dihedral angles of 87.6 (7)/83.64 (7), 74.3 (7) and 88.3 (7)° with respect to the corresponding PdN4 plane. International Union of Crystallography 2013-01-12 /pmc/articles/PMC3569194/ /pubmed/23424438 http://dx.doi.org/10.1107/S1600536813000573 Text en © Wolfgang Imhof 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
repository_type Open Access Journal
institution_category Foreign Institution
institution US National Center for Biotechnology Information
building NCBI PubMed
collection Online Access
language English
format Online
author Imhof, Wolfgang
spellingShingle Imhof, Wolfgang
Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II)
author_facet Imhof, Wolfgang
author_sort Imhof, Wolfgang
title Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II)
title_short Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II)
title_full Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II)
title_fullStr Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II)
title_full_unstemmed Bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(II)
title_sort bis{2-[(2,4,6-trimethyl­phen­yl)imino­methyl]pyrrol-1-ido}palladium(ii)
description The title compound, [Pd(C14H15N2)2], is a square-planar palladium complex composed of two deprotonated pyrrole-2-carbaldimine ligands coordinating a central PdII atom. In the crystal, three crystallographically independent complex mol­ecules are observed, one of which is located in a general position, whereas the PdII atoms of the other mol­ecules are situated on crystallographic inversion centers. The aromatic substituents at the imine N atoms in the three mol­ecules show dihedral angles of 87.6 (7)/83.64 (7), 74.3 (7) and 88.3 (7)° with respect to the corresponding PdN4 plane.
publisher International Union of Crystallography
publishDate 2013
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569194/
_version_ 1611953809199726592

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