[Bis[μ-bis­(diphenyl­phosphino)methane-1:2κ2 P:P′]-bis­(nitrito-κ2 O,O′)]disilver(I) acetonitrile disolvate

[Bis[μ-bis­(diphenyl­phosphino)methane-1:2κ2 P:P′]-bis­(nitrito-κ2 O,O′)]disilver(I) acetonitrile disolvate

The title complex, [Ag2(NO2)2(C25H22P2)2]·2CH3CN, is a centrosymmetric dimer in which two bis(diphenylphosphino)methane ligands bridge two Ag+ ions, forming an eight-membered ring with a short Ag⋯Ag separation of 3.1809 (5) Å. The distorted P2O2 coordination of the cation is completed by two O-donor...

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Bibliographic Details
Main Authors: Yang, Xue, Huang, Xu, Qiu, Qi-Ming, Jin, Qiong-Hua, Zhang, Cun-Lin
Format: Online
Language:English
Published: International Union of Crystallography 2012
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515120/

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515120/

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