N-(2-Bromobenzyl)cinchoninium bromide
The title compound {systematic name: 1-(2-bromobenzyl)-5-ethenyl-2-[hydroxy(quinolin-4-yl)methyl]-1-azabicyclo[2.2.2]octan-1-ium bromide}, C26H28BrN2O+·Br−, is a chiral quaternary ammonium salt of one of the Cinchona alkaloids. The planes of the quinoline and of the bromobenzyl substituent a...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2012
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435830/ |
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pubmed-3435830 |
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oai_dc |
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pubmed-34358302012-09-11 N-(2-Bromobenzyl)cinchoninium bromide Skórska-Stania, Agnieszka Jezierska-Zięba, Magdalena Kąkol, Barbara Fedoryński, Michał Oleksyn, Barbara J. Organic Papers The title compound {systematic name: 1-(2-bromobenzyl)-5-ethenyl-2-[hydroxy(quinolin-4-yl)methyl]-1-azabicyclo[2.2.2]octan-1-ium bromide}, C26H28BrN2O+·Br−, is a chiral quaternary ammonium salt of one of the Cinchona alkaloids. The planes of the quinoline and of the bromobenzyl substituent are inclined to one another by 9.11 (9)°. A weak intramolecular C—H⋯O hydrogen bond occurs. The crystal structure features strong O—H⋯Br hydrogen bonds and weak C—H⋯Br interactions. International Union of Crystallography 2012-08-31 /pmc/articles/PMC3435830/ /pubmed/22969676 http://dx.doi.org/10.1107/S160053681203646X Text en © Skórska-Stania et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Skórska-Stania, Agnieszka Jezierska-Zięba, Magdalena Kąkol, Barbara Fedoryński, Michał Oleksyn, Barbara J. |
| spellingShingle |
Skórska-Stania, Agnieszka Jezierska-Zięba, Magdalena Kąkol, Barbara Fedoryński, Michał Oleksyn, Barbara J. N-(2-Bromobenzyl)cinchoninium bromide |
| author_facet |
Skórska-Stania, Agnieszka Jezierska-Zięba, Magdalena Kąkol, Barbara Fedoryński, Michał Oleksyn, Barbara J. |
| author_sort |
Skórska-Stania, Agnieszka |
| title |
N-(2-Bromobenzyl)cinchoninium bromide |
| title_short |
N-(2-Bromobenzyl)cinchoninium bromide |
| title_full |
N-(2-Bromobenzyl)cinchoninium bromide |
| title_fullStr |
N-(2-Bromobenzyl)cinchoninium bromide |
| title_full_unstemmed |
N-(2-Bromobenzyl)cinchoninium bromide |
| title_sort |
n-(2-bromobenzyl)cinchoninium bromide |
| description |
The title compound {systematic name: 1-(2-bromobenzyl)-5-ethenyl-2-[hydroxy(quinolin-4-yl)methyl]-1-azabicyclo[2.2.2]octan-1-ium bromide}, C26H28BrN2O+·Br−, is a chiral quaternary ammonium salt of one of the Cinchona alkaloids. The planes of the quinoline and of the bromobenzyl substituent are inclined to one another by 9.11 (9)°. A weak intramolecular C—H⋯O hydrogen bond occurs. The crystal structure features strong O—H⋯Br hydrogen bonds and weak C—H⋯Br interactions. |
| publisher |
International Union of Crystallography |
| publishDate |
2012 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435830/ |
| _version_ |
1611554810037796864 |