Investigation of the non-volatile resistance change in noncentrosymmetric compounds

Coexistence of polarization and resistance-switching characteristics in single compounds has been long inspired scientific and technological interests. Here, we report the non-volatile resistance change in noncentrosymmetric compounds investigated by using defect nanotechnology and contact engineeri...

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Main Authors: Herng, T. S., Kumar, A., Ong, C. S., Feng, Y. P., Lu, Y. H., Zeng, K. Y., Ding, J.
Format: Online
Language:English
Published: Nature Publishing Group 2012
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3421435/
id pubmed-3421435
recordtype oai_dc
spelling pubmed-34214352012-08-17 Investigation of the non-volatile resistance change in noncentrosymmetric compounds Herng, T. S. Kumar, A. Ong, C. S. Feng, Y. P. Lu, Y. H. Zeng, K. Y. Ding, J. Article Coexistence of polarization and resistance-switching characteristics in single compounds has been long inspired scientific and technological interests. Here, we report the non-volatile resistance change in noncentrosymmetric compounds investigated by using defect nanotechnology and contact engineering. Using a noncentrosymmetric material of ZnO as example, we first transformed ZnO into high resistance state. Then ZnO electrical polarization was probed and its domains polarized 180° along the [001]-axis with long-lasting memory effect (>25 hours). Based on our experimental observations, we have developed a vacancy-mediated pseudoferroelectricity model. Our first-principle calculations propose that vacancy defects initiate a spontaneous inverted domains nucleation at grain boundaries, and then they grow in the presence of an electrical field. The propagation of inverted domains follows the scanning tip motion under applied electrical field, leading to the growth of polarized domains over large areas. Nature Publishing Group 2012-08-17 /pmc/articles/PMC3421435/ /pubmed/22905318 http://dx.doi.org/10.1038/srep00587 Text en Copyright © 2012, Macmillan Publishers Limited. All rights reserved http://creativecommons.org/licenses/by-nc-nd/3.0/ This work is licensed under a Creative Commons Attribution-NonCommercial-No Derivative Works 3.0 Unported License. To view a copy of this license, visit http://creativecommons.org/licenses/by-nc-nd/3.0/
repository_type Open Access Journal
institution_category Foreign Institution
institution US National Center for Biotechnology Information
building NCBI PubMed
collection Online Access
language English
format Online
author Herng, T. S.
Kumar, A.
Ong, C. S.
Feng, Y. P.
Lu, Y. H.
Zeng, K. Y.
Ding, J.
spellingShingle Herng, T. S.
Kumar, A.
Ong, C. S.
Feng, Y. P.
Lu, Y. H.
Zeng, K. Y.
Ding, J.
Investigation of the non-volatile resistance change in noncentrosymmetric compounds
author_facet Herng, T. S.
Kumar, A.
Ong, C. S.
Feng, Y. P.
Lu, Y. H.
Zeng, K. Y.
Ding, J.
author_sort Herng, T. S.
title Investigation of the non-volatile resistance change in noncentrosymmetric compounds
title_short Investigation of the non-volatile resistance change in noncentrosymmetric compounds
title_full Investigation of the non-volatile resistance change in noncentrosymmetric compounds
title_fullStr Investigation of the non-volatile resistance change in noncentrosymmetric compounds
title_full_unstemmed Investigation of the non-volatile resistance change in noncentrosymmetric compounds
title_sort investigation of the non-volatile resistance change in noncentrosymmetric compounds
description Coexistence of polarization and resistance-switching characteristics in single compounds has been long inspired scientific and technological interests. Here, we report the non-volatile resistance change in noncentrosymmetric compounds investigated by using defect nanotechnology and contact engineering. Using a noncentrosymmetric material of ZnO as example, we first transformed ZnO into high resistance state. Then ZnO electrical polarization was probed and its domains polarized 180° along the [001]-axis with long-lasting memory effect (>25 hours). Based on our experimental observations, we have developed a vacancy-mediated pseudoferroelectricity model. Our first-principle calculations propose that vacancy defects initiate a spontaneous inverted domains nucleation at grain boundaries, and then they grow in the presence of an electrical field. The propagation of inverted domains follows the scanning tip motion under applied electrical field, leading to the growth of polarized domains over large areas.
publisher Nature Publishing Group
publishDate 2012
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3421435/
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