2-[(4-Methoxy-2-nitrophenyl)iminomethyl]phenol
The crystal structure of the title compound, C14H12N2O4, contains four crystallographically independent molecules in the asymmetric unit. All the molecules have similar conformations; the dihedral angles between the aromatic rings are 33.1 (1), 33.76 (9), 31.41 (9) and 32.56 (10)°. Intramolecular...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2012
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414359/ |
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pubmed-3414359 |
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oai_dc |
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pubmed-34143592012-08-17 2-[(4-Methoxy-2-nitrophenyl)iminomethyl]phenol Khalaji, Aliakbar Dehno Nikookar, Mahsa Fejfarová, Karla Dušek, Michal Organic Papers The crystal structure of the title compound, C14H12N2O4, contains four crystallographically independent molecules in the asymmetric unit. All the molecules have similar conformations; the dihedral angles between the aromatic rings are 33.1 (1), 33.76 (9), 31.41 (9) and 32.56 (10)°. Intramolecular O—H⋯N hydrogen bonds form S(6) ring motifs in each molecule. In the crystal, there are two pairs of pseudo-inversion-related molecules. Along the c axis, molecules are stacked with π–π interactions between the 2-hydroxyphenyl and 4-methoxy-2-nitrophenyl rings [centroid–centroid distances = 3.5441 (12)–3.7698 (12) Å]. International Union of Crystallography 2012-07-14 /pmc/articles/PMC3414359/ /pubmed/22904892 http://dx.doi.org/10.1107/S1600536812031212 Text en © Khalaji et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Khalaji, Aliakbar Dehno Nikookar, Mahsa Fejfarová, Karla Dušek, Michal |
| spellingShingle |
Khalaji, Aliakbar Dehno Nikookar, Mahsa Fejfarová, Karla Dušek, Michal 2-[(4-Methoxy-2-nitrophenyl)iminomethyl]phenol |
| author_facet |
Khalaji, Aliakbar Dehno Nikookar, Mahsa Fejfarová, Karla Dušek, Michal |
| author_sort |
Khalaji, Aliakbar Dehno |
| title |
2-[(4-Methoxy-2-nitrophenyl)iminomethyl]phenol |
| title_short |
2-[(4-Methoxy-2-nitrophenyl)iminomethyl]phenol |
| title_full |
2-[(4-Methoxy-2-nitrophenyl)iminomethyl]phenol |
| title_fullStr |
2-[(4-Methoxy-2-nitrophenyl)iminomethyl]phenol |
| title_full_unstemmed |
2-[(4-Methoxy-2-nitrophenyl)iminomethyl]phenol |
| title_sort |
2-[(4-methoxy-2-nitrophenyl)iminomethyl]phenol |
| description |
The crystal structure of the title compound, C14H12N2O4, contains four crystallographically independent molecules in the asymmetric unit. All the molecules have similar conformations; the dihedral angles between the aromatic rings are 33.1 (1), 33.76 (9), 31.41 (9) and 32.56 (10)°. Intramolecular O—H⋯N hydrogen bonds form S(6) ring motifs in each molecule. In the crystal, there are two pairs of pseudo-inversion-related molecules. Along the c axis, molecules are stacked with π–π interactions between the 2-hydroxyphenyl and 4-methoxy-2-nitrophenyl rings [centroid–centroid distances = 3.5441 (12)–3.7698 (12) Å]. |
| publisher |
International Union of Crystallography |
| publishDate |
2012 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414359/ |
| _version_ |
1611548423907966976 |