(Cinnamato-κ2 O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4 N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate
In the title compound, [Ni(C9H7O2)(C16H36N4)]ClO4·H2O, the macrocyclic 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane ligand (L) folds around the NiII atom, which is also chelated by the carboxylate group. The geometry is a distorted N4O2 octahedron. In the crystal, adjacent mol...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2012
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414150/ |
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pubmed-3414150 |
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oai_dc |
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pubmed-34141502012-08-17 (Cinnamato-κ2 O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4 N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate Gao, Qiang Cao, Yi-Cheng Metal-Organic Papers In the title compound, [Ni(C9H7O2)(C16H36N4)]ClO4·H2O, the macrocyclic 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane ligand (L) folds around the NiII atom, which is also chelated by the carboxylate group. The geometry is a distorted N4O2 octahedron. In the crystal, adjacent molecules are connected by O—H⋯O and N—H⋯O hydrogen bonds into a zigzag chain parallel to [010]. International Union of Crystallography 2012-07-21 /pmc/articles/PMC3414150/ /pubmed/22904757 http://dx.doi.org/10.1107/S1600536812032175 Text en © Gao and Cao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Gao, Qiang Cao, Yi-Cheng |
| spellingShingle |
Gao, Qiang Cao, Yi-Cheng (Cinnamato-κ2 O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4 N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| author_facet |
Gao, Qiang Cao, Yi-Cheng |
| author_sort |
Gao, Qiang |
| title |
(Cinnamato-κ2
O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4
N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_short |
(Cinnamato-κ2
O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4
N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_full |
(Cinnamato-κ2
O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4
N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_fullStr |
(Cinnamato-κ2
O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4
N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_full_unstemmed |
(Cinnamato-κ2
O,O′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4
N,N′,N′′,N′′′)nickel(II) perchlorate monohydrate |
| title_sort |
(cinnamato-κ2
o,o′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4
n,n′,n′′,n′′′)nickel(ii) perchlorate monohydrate |
| description |
In the title compound, [Ni(C9H7O2)(C16H36N4)]ClO4·H2O, the macrocyclic 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane ligand (L) folds around the NiII atom, which is also chelated by the carboxylate group. The geometry is a distorted N4O2 octahedron. In the crystal, adjacent molecules are connected by O—H⋯O and N—H⋯O hydrogen bonds into a zigzag chain parallel to [010]. |
| publisher |
International Union of Crystallography |
| publishDate |
2012 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3414150/ |
| _version_ |
1611548321933950976 |