Diaquabis(nitrato-κ2 O,O′)bis(pyrazine-2-carboxamide-κN 4)cadmium–pyrazine-2-carboxamide (1/2)
In the title compound, [Cd(NO3)2(C5H5N3O)2(H2O)2]·2C5H5N3O, the CdII cation is located on a twofold rotation axis and is coordinated by two pyrazine-2-carboxamide ligands and two water molecules and chelated by two nitrate anions in a distorted square-antiprismatic geometry. Extensive intermolecu...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2012
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393246/ |
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pubmed-3393246 |
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oai_dc |
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pubmed-33932462012-07-17 Diaquabis(nitrato-κ2 O,O′)bis(pyrazine-2-carboxamide-κN 4)cadmium–pyrazine-2-carboxamide (1/2) Shirvan, Sadif A. Haydari Dezfuli, Sara Metal-Organic Papers In the title compound, [Cd(NO3)2(C5H5N3O)2(H2O)2]·2C5H5N3O, the CdII cation is located on a twofold rotation axis and is coordinated by two pyrazine-2-carboxamide ligands and two water molecules and chelated by two nitrate anions in a distorted square-antiprismatic geometry. Extensive intermolecular N—H⋯O, N—H⋯N, O—H⋯O and O—H⋯N hydrogen bonds, as well as weak intermolecular C—H⋯N and C—H⋯O interactions occur in the crystal. π–π stacking between between pyrazine rings of coordinating ligands and lattice molecules [centroid–centroid distance = 3.5669 (14) Å] may further stabilize the structure. International Union of Crystallography 2012-06-30 /pmc/articles/PMC3393246/ /pubmed/22807706 http://dx.doi.org/10.1107/S1600536812028577 Text en © Shirvan and Haydari Dezfuli 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Shirvan, Sadif A. Haydari Dezfuli, Sara |
| spellingShingle |
Shirvan, Sadif A. Haydari Dezfuli, Sara Diaquabis(nitrato-κ2 O,O′)bis(pyrazine-2-carboxamide-κN 4)cadmium–pyrazine-2-carboxamide (1/2) |
| author_facet |
Shirvan, Sadif A. Haydari Dezfuli, Sara |
| author_sort |
Shirvan, Sadif A. |
| title |
Diaquabis(nitrato-κ2
O,O′)bis(pyrazine-2-carboxamide-κN
4)cadmium–pyrazine-2-carboxamide (1/2) |
| title_short |
Diaquabis(nitrato-κ2
O,O′)bis(pyrazine-2-carboxamide-κN
4)cadmium–pyrazine-2-carboxamide (1/2) |
| title_full |
Diaquabis(nitrato-κ2
O,O′)bis(pyrazine-2-carboxamide-κN
4)cadmium–pyrazine-2-carboxamide (1/2) |
| title_fullStr |
Diaquabis(nitrato-κ2
O,O′)bis(pyrazine-2-carboxamide-κN
4)cadmium–pyrazine-2-carboxamide (1/2) |
| title_full_unstemmed |
Diaquabis(nitrato-κ2
O,O′)bis(pyrazine-2-carboxamide-κN
4)cadmium–pyrazine-2-carboxamide (1/2) |
| title_sort |
diaquabis(nitrato-κ2
o,o′)bis(pyrazine-2-carboxamide-κn
4)cadmium–pyrazine-2-carboxamide (1/2) |
| description |
In the title compound, [Cd(NO3)2(C5H5N3O)2(H2O)2]·2C5H5N3O, the CdII cation is located on a twofold rotation axis and is coordinated by two pyrazine-2-carboxamide ligands and two water molecules and chelated by two nitrate anions in a distorted square-antiprismatic geometry. Extensive intermolecular N—H⋯O, N—H⋯N, O—H⋯O and O—H⋯N hydrogen bonds, as well as weak intermolecular C—H⋯N and C—H⋯O interactions occur in the crystal. π–π stacking between between pyrazine rings of coordinating ligands and lattice molecules [centroid–centroid distance = 3.5669 (14) Å] may further stabilize the structure. |
| publisher |
International Union of Crystallography |
| publishDate |
2012 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393246/ |
| _version_ |
1611541999617310720 |