[2-({Benzyl[2-(benzyl{5-methyl-2-oxido-3-[(pyridin-2-ylmethyl)iminomethyl]benzyl}amino)ethyl]azaniumyl}methyl)-4-methyl-6-[(pyridin-2-ylmethyl)iminomethyl]phenolato]nickel(II) perchlorate methanol disolvate
In the solvated title complex, [Ni(C46H47N6O2)]ClO4·2CH4O, the coordination sphere around the NiII ion can be described as distorted cis-NiO2N4 octahedral defined by two phenolate O atoms and four N atoms from the hexadentate ligand. An intramolecular bifurcated N—H⋯(N,O) hydrogen bond helps to e...
Main Authors: | , , |
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Format: | Online |
Language: | English |
Published: |
International Union of Crystallography
2012
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Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379195/ |