Poly[(μ3-quinoline-6-carboxylato-κ3 N:O:O′)silver(I)]
In the title coordination polymer, [Ag(C10H6NO2)]n, the AgI cation is coordinated by two O atoms and one N atom from three 6-quinolinecarboxylate anions in a distorted T-shaped AgNO2 geometry, in which the O—Ag—O angle is 160.44 (9)°. The 6-quinolinecarboxylate anion bridges three Ag+ cations, f...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2012
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379188/ |
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pubmed-3379188 |
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oai_dc |
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pubmed-33791882012-06-20 Poly[(μ3-quinoline-6-carboxylato-κ3 N:O:O′)silver(I)] Yeh, Chun-Wei Jong, Ay Tsou, Chi-Hui Huang, Fu-Chang Suen, Maw-Cherng Metal-Organic Papers In the title coordination polymer, [Ag(C10H6NO2)]n, the AgI cation is coordinated by two O atoms and one N atom from three 6-quinolinecarboxylate anions in a distorted T-shaped AgNO2 geometry, in which the O—Ag—O angle is 160.44 (9)°. The 6-quinolinecarboxylate anion bridges three Ag+ cations, forming a nearly planar polymeric sheet parallel to (101). The distance between Ag+ cations bridged by the carboxyl group is 2.9200 (5) Å. In the crystal, π–π stacking is observed between parallel quinoline ring systems, the centroid–centroid distance being 3.7735 (16) Å. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379188/ /pubmed/22719386 http://dx.doi.org/10.1107/S1600536812023835 Text en © Yeh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Yeh, Chun-Wei Jong, Ay Tsou, Chi-Hui Huang, Fu-Chang Suen, Maw-Cherng |
| spellingShingle |
Yeh, Chun-Wei Jong, Ay Tsou, Chi-Hui Huang, Fu-Chang Suen, Maw-Cherng Poly[(μ3-quinoline-6-carboxylato-κ3 N:O:O′)silver(I)] |
| author_facet |
Yeh, Chun-Wei Jong, Ay Tsou, Chi-Hui Huang, Fu-Chang Suen, Maw-Cherng |
| author_sort |
Yeh, Chun-Wei |
| title |
Poly[(μ3-quinoline-6-carboxylato-κ3
N:O:O′)silver(I)] |
| title_short |
Poly[(μ3-quinoline-6-carboxylato-κ3
N:O:O′)silver(I)] |
| title_full |
Poly[(μ3-quinoline-6-carboxylato-κ3
N:O:O′)silver(I)] |
| title_fullStr |
Poly[(μ3-quinoline-6-carboxylato-κ3
N:O:O′)silver(I)] |
| title_full_unstemmed |
Poly[(μ3-quinoline-6-carboxylato-κ3
N:O:O′)silver(I)] |
| title_sort |
poly[(μ3-quinoline-6-carboxylato-κ3
n:o:o′)silver(i)] |
| description |
In the title coordination polymer, [Ag(C10H6NO2)]n, the AgI cation is coordinated by two O atoms and one N atom from three 6-quinolinecarboxylate anions in a distorted T-shaped AgNO2 geometry, in which the O—Ag—O angle is 160.44 (9)°. The 6-quinolinecarboxylate anion bridges three Ag+ cations, forming a nearly planar polymeric sheet parallel to (101). The distance between Ag+ cations bridged by the carboxyl group is 2.9200 (5) Å. In the crystal, π–π stacking is observed between parallel quinoline ring systems, the centroid–centroid distance being 3.7735 (16) Å. |
| publisher |
International Union of Crystallography |
| publishDate |
2012 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379188/ |
| _version_ |
1611537966816034816 |