catena-Poly[[[bis(nitrato-κO)copper(II)]-bis[μ-1,3-bis(imidazol-1-yl)-5-methylbenzene-κ2 N 3:N 3′]] dihydrate]
In the title complex, {[Cu(NO3)2(C13H12N4)2]·2H2O}n, the CuII atom is located on a crystallographic center of symmetry and adopts an N4O2 octahedral coordination geometry with four imidazole N atoms in the equatorial sites and two O atoms in the axial sites. The dihedral angles between the central...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2012
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379180/ |
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pubmed-3379180 |
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oai_dc |
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pubmed-33791802012-06-20 catena-Poly[[[bis(nitrato-κO)copper(II)]-bis[μ-1,3-bis(imidazol-1-yl)-5-methylbenzene-κ2 N 3:N 3′]] dihydrate] Liu, Guang-Xiang Metal-Organic Papers In the title complex, {[Cu(NO3)2(C13H12N4)2]·2H2O}n, the CuII atom is located on a crystallographic center of symmetry and adopts an N4O2 octahedral coordination geometry with four imidazole N atoms in the equatorial sites and two O atoms in the axial sites. The dihedral angles between the central benzene ring and the imidazole rings are 4.93 (11) and 46.08 (12)°. The 1,3-bis(imidazol-1-yl)-5-methylbenzene ligand is bis-monodentate, linking symmetry-related CuII atoms into sheets in the bc plane. These sheets are further bridged into a three-dimensional supramolecular structure by O—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379180/ /pubmed/22719378 http://dx.doi.org/10.1107/S1600536812023628 Text en © Guang-Xiang Liu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Liu, Guang-Xiang |
| spellingShingle |
Liu, Guang-Xiang catena-Poly[[[bis(nitrato-κO)copper(II)]-bis[μ-1,3-bis(imidazol-1-yl)-5-methylbenzene-κ2 N 3:N 3′]] dihydrate] |
| author_facet |
Liu, Guang-Xiang |
| author_sort |
Liu, Guang-Xiang |
| title |
catena-Poly[[[bis(nitrato-κO)copper(II)]-bis[μ-1,3-bis(imidazol-1-yl)-5-methylbenzene-κ2
N
3:N
3′]] dihydrate] |
| title_short |
catena-Poly[[[bis(nitrato-κO)copper(II)]-bis[μ-1,3-bis(imidazol-1-yl)-5-methylbenzene-κ2
N
3:N
3′]] dihydrate] |
| title_full |
catena-Poly[[[bis(nitrato-κO)copper(II)]-bis[μ-1,3-bis(imidazol-1-yl)-5-methylbenzene-κ2
N
3:N
3′]] dihydrate] |
| title_fullStr |
catena-Poly[[[bis(nitrato-κO)copper(II)]-bis[μ-1,3-bis(imidazol-1-yl)-5-methylbenzene-κ2
N
3:N
3′]] dihydrate] |
| title_full_unstemmed |
catena-Poly[[[bis(nitrato-κO)copper(II)]-bis[μ-1,3-bis(imidazol-1-yl)-5-methylbenzene-κ2
N
3:N
3′]] dihydrate] |
| title_sort |
catena-poly[[[bis(nitrato-κo)copper(ii)]-bis[μ-1,3-bis(imidazol-1-yl)-5-methylbenzene-κ2
n
3:n
3′]] dihydrate] |
| description |
In the title complex, {[Cu(NO3)2(C13H12N4)2]·2H2O}n, the CuII atom is located on a crystallographic center of symmetry and adopts an N4O2 octahedral coordination geometry with four imidazole N atoms in the equatorial sites and two O atoms in the axial sites. The dihedral angles between the central benzene ring and the imidazole rings are 4.93 (11) and 46.08 (12)°. The 1,3-bis(imidazol-1-yl)-5-methylbenzene ligand is bis-monodentate, linking symmetry-related CuII atoms into sheets in the bc plane. These sheets are further bridged into a three-dimensional supramolecular structure by O—H⋯O and C—H⋯O hydrogen bonds. |
| publisher |
International Union of Crystallography |
| publishDate |
2012 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379180/ |
| _version_ |
1611537962359586816 |