catena-Poly[[[diaqua(1,10-phenanthroline-κ2 N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2 O 3:O 1] sesquihydrate]
The 1,10-phenanthroline-chelated CoII atom in the polymeric title compound, {[Co(C7H4O6S)(C12H8N2)(H2O)2]·1.5H2O}n, is connected to the sulfonate O atom of one 4-hydroxy-3-sulfonatobenzoate dianion and to the carboxylate O atom of another dianion. It is also coordinated by two water molecules in...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2012
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379066/ |
| id |
pubmed-3379066 |
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| recordtype |
oai_dc |
| spelling |
pubmed-33790662012-06-20 catena-Poly[[[diaqua(1,10-phenanthroline-κ2 N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2 O 3:O 1] sesquihydrate] Fang, Xiang-Qian Gao, Shan Ng, Seik Weng Metal-Organic Papers The 1,10-phenanthroline-chelated CoII atom in the polymeric title compound, {[Co(C7H4O6S)(C12H8N2)(H2O)2]·1.5H2O}n, is connected to the sulfonate O atom of one 4-hydroxy-3-sulfonatobenzoate dianion and to the carboxylate O atom of another dianion. It is also coordinated by two water molecules in a trans-CoN2O4 octahedral environment. The dianion links adjacent metal atoms into a chain running along [110]. The chains are linked by O—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2012-05-02 /pmc/articles/PMC3379066/ /pubmed/22719287 http://dx.doi.org/10.1107/S1600536812018752 Text en © Fang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Fang, Xiang-Qian Gao, Shan Ng, Seik Weng |
| spellingShingle |
Fang, Xiang-Qian Gao, Shan Ng, Seik Weng catena-Poly[[[diaqua(1,10-phenanthroline-κ2 N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2 O 3:O 1] sesquihydrate] |
| author_facet |
Fang, Xiang-Qian Gao, Shan Ng, Seik Weng |
| author_sort |
Fang, Xiang-Qian |
| title |
catena-Poly[[[diaqua(1,10-phenanthroline-κ2
N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2
O
3:O
1] sesquihydrate] |
| title_short |
catena-Poly[[[diaqua(1,10-phenanthroline-κ2
N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2
O
3:O
1] sesquihydrate] |
| title_full |
catena-Poly[[[diaqua(1,10-phenanthroline-κ2
N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2
O
3:O
1] sesquihydrate] |
| title_fullStr |
catena-Poly[[[diaqua(1,10-phenanthroline-κ2
N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2
O
3:O
1] sesquihydrate] |
| title_full_unstemmed |
catena-Poly[[[diaqua(1,10-phenanthroline-κ2
N,N′)cobalt(II)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2
O
3:O
1] sesquihydrate] |
| title_sort |
catena-poly[[[diaqua(1,10-phenanthroline-κ2
n,n′)cobalt(ii)]-μ-4-hydroxy-3-sulfonatobenzoato-κ2
o
3:o
1] sesquihydrate] |
| description |
The 1,10-phenanthroline-chelated CoII atom in the polymeric title compound, {[Co(C7H4O6S)(C12H8N2)(H2O)2]·1.5H2O}n, is connected to the sulfonate O atom of one 4-hydroxy-3-sulfonatobenzoate dianion and to the carboxylate O atom of another dianion. It is also coordinated by two water molecules in a trans-CoN2O4 octahedral environment. The dianion links adjacent metal atoms into a chain running along [110]. The chains are linked by O—H⋯O hydrogen bonds into a three-dimensional network. |
| publisher |
International Union of Crystallography |
| publishDate |
2012 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379066/ |
| _version_ |
1611537906538643456 |