N-(3,4-Difluorophenyl)-2,2-diphenylacetamide
In the title compound, C20H15F2NO, the mean plane of the acetamide group makes dihedral angles of 88.26 (6), 78.30 (7) and 9.83 (6)° with the two terminal benzene rings and difluoro-substituted benzene ring, respectively. One F atom is disordered over two orientations rotated by 180°, with a site-oc...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2012
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344483/ |
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pubmed-3344483 |
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pubmed-33444832012-05-15 N-(3,4-Difluorophenyl)-2,2-diphenylacetamide Fun, Hoong-Kun Ooi, Chin Wei Nayak, Prakash S. Narayana, B. Sarojini, B. K. Organic Papers In the title compound, C20H15F2NO, the mean plane of the acetamide group makes dihedral angles of 88.26 (6), 78.30 (7) and 9.83 (6)° with the two terminal benzene rings and difluoro-substituted benzene ring, respectively. One F atom is disordered over two orientations rotated by 180°, with a site-occupancy ratio of 0.557 (2):0.443 (2). An intramolecular C—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked via N—H⋯O hydrogen bonds into chains along the c axis. The crystal structure is further consolidated by C—H⋯π interactions. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344483/ /pubmed/22590245 http://dx.doi.org/10.1107/S1600536812014675 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Fun, Hoong-Kun Ooi, Chin Wei Nayak, Prakash S. Narayana, B. Sarojini, B. K. |
| spellingShingle |
Fun, Hoong-Kun Ooi, Chin Wei Nayak, Prakash S. Narayana, B. Sarojini, B. K. N-(3,4-Difluorophenyl)-2,2-diphenylacetamide |
| author_facet |
Fun, Hoong-Kun Ooi, Chin Wei Nayak, Prakash S. Narayana, B. Sarojini, B. K. |
| author_sort |
Fun, Hoong-Kun |
| title |
N-(3,4-Difluorophenyl)-2,2-diphenylacetamide |
| title_short |
N-(3,4-Difluorophenyl)-2,2-diphenylacetamide |
| title_full |
N-(3,4-Difluorophenyl)-2,2-diphenylacetamide |
| title_fullStr |
N-(3,4-Difluorophenyl)-2,2-diphenylacetamide |
| title_full_unstemmed |
N-(3,4-Difluorophenyl)-2,2-diphenylacetamide |
| title_sort |
n-(3,4-difluorophenyl)-2,2-diphenylacetamide |
| description |
In the title compound, C20H15F2NO, the mean plane of the acetamide group makes dihedral angles of 88.26 (6), 78.30 (7) and 9.83 (6)° with the two terminal benzene rings and difluoro-substituted benzene ring, respectively. One F atom is disordered over two orientations rotated by 180°, with a site-occupancy ratio of 0.557 (2):0.443 (2). An intramolecular C—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked via N—H⋯O hydrogen bonds into chains along the c axis. The crystal structure is further consolidated by C—H⋯π interactions. |
| publisher |
International Union of Crystallography |
| publishDate |
2012 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344483/ |
| _version_ |
1611527400000061440 |