catena-Poly[[diaquabis(2-ethyl-1H-imidazole-κN 3)cadmium]-μ-sulfato-κ2 O:O′]
In the title one-dimensional coordination polymer, [Cd(SO4)(C5H8N2)2(H2O)2]n, the CdII atom (site symmetry 2) is coordinated by two sulfate O atoms, two water molecules and two 2-ethylimidazole ligands in a distorted cis-CdN2O4 octahedral geometry. The water molecules have a cis disposition. The...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2012
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344375/ |
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pubmed-3344375 |
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oai_dc |
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pubmed-33443752012-05-15 catena-Poly[[diaquabis(2-ethyl-1H-imidazole-κN 3)cadmium]-μ-sulfato-κ2 O:O′] Yu, Chua-Hua Metal-Organic Papers In the title one-dimensional coordination polymer, [Cd(SO4)(C5H8N2)2(H2O)2]n, the CdII atom (site symmetry 2) is coordinated by two sulfate O atoms, two water molecules and two 2-ethylimidazole ligands in a distorted cis-CdN2O4 octahedral geometry. The water molecules have a cis disposition. The bridging sulfate ions (site symmetry 2) link the CdII ions into a polymeric chain extending along [001]. The chains are linked by N—H⋯O and O—H⋯O hydrogen bonds. The terminal –CH3 group of the ligand is disordered over two orientations in a 0.61 (5):0.39 (5) ratio. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344375/ /pubmed/22590141 http://dx.doi.org/10.1107/S1600536812017059 Text en © Chua-Hua Yu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Yu, Chua-Hua |
| spellingShingle |
Yu, Chua-Hua catena-Poly[[diaquabis(2-ethyl-1H-imidazole-κN 3)cadmium]-μ-sulfato-κ2 O:O′] |
| author_facet |
Yu, Chua-Hua |
| author_sort |
Yu, Chua-Hua |
| title |
catena-Poly[[diaquabis(2-ethyl-1H-imidazole-κN
3)cadmium]-μ-sulfato-κ2
O:O′] |
| title_short |
catena-Poly[[diaquabis(2-ethyl-1H-imidazole-κN
3)cadmium]-μ-sulfato-κ2
O:O′] |
| title_full |
catena-Poly[[diaquabis(2-ethyl-1H-imidazole-κN
3)cadmium]-μ-sulfato-κ2
O:O′] |
| title_fullStr |
catena-Poly[[diaquabis(2-ethyl-1H-imidazole-κN
3)cadmium]-μ-sulfato-κ2
O:O′] |
| title_full_unstemmed |
catena-Poly[[diaquabis(2-ethyl-1H-imidazole-κN
3)cadmium]-μ-sulfato-κ2
O:O′] |
| title_sort |
catena-poly[[diaquabis(2-ethyl-1h-imidazole-κn
3)cadmium]-μ-sulfato-κ2
o:o′] |
| description |
In the title one-dimensional coordination polymer, [Cd(SO4)(C5H8N2)2(H2O)2]n, the CdII atom (site symmetry 2) is coordinated by two sulfate O atoms, two water molecules and two 2-ethylimidazole ligands in a distorted cis-CdN2O4 octahedral geometry. The water molecules have a cis disposition. The bridging sulfate ions (site symmetry 2) link the CdII ions into a polymeric chain extending along [001]. The chains are linked by N—H⋯O and O—H⋯O hydrogen bonds. The terminal –CH3 group of the ligand is disordered over two orientations in a 0.61 (5):0.39 (5) ratio. |
| publisher |
International Union of Crystallography |
| publishDate |
2012 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344375/ |
| _version_ |
1611527339543363584 |