Bis(acetato-κO)bis(pyridine-2-aldoxime-κ2 N,N′)nickel(II)
In the mononuclear title compound, [Ni(CH3COO)2(C6H6N2O)2], the NiII atom is coordinated by two pyridine-2-aldoxime (PaoH) ligands and two acetate groups, with cis coordination for the pairs of identical ligands. While each acetate group binds to the NiII atom by one O atom, each PaoH chelates the N...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2012
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344309/ |
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pubmed-3344309 |
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pubmed-33443092012-05-15 Bis(acetato-κO)bis(pyridine-2-aldoxime-κ2 N,N′)nickel(II) Si, Youtao Metal-Organic Papers In the mononuclear title compound, [Ni(CH3COO)2(C6H6N2O)2], the NiII atom is coordinated by two pyridine-2-aldoxime (PaoH) ligands and two acetate groups, with cis coordination for the pairs of identical ligands. While each acetate group binds to the NiII atom by one O atom, each PaoH chelates the NiII atom through two N atoms. The O atom on PaoH is not deprotonated and does not participate in bonding to the NiII atom. Thus, the NiII atom exhibits an octahedral environment. Intramolecular O—H⋯O hydrogen-bonding interactions and intermolecular C—H⋯O hydrogen-bonding interactions are present in the structure. Adjacent molecules pack along [100] through van der Waals forces. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344309/ /pubmed/22590075 http://dx.doi.org/10.1107/S1600536812014377 Text en © Youtao Si 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Si, Youtao |
| spellingShingle |
Si, Youtao Bis(acetato-κO)bis(pyridine-2-aldoxime-κ2 N,N′)nickel(II) |
| author_facet |
Si, Youtao |
| author_sort |
Si, Youtao |
| title |
Bis(acetato-κO)bis(pyridine-2-aldoxime-κ2
N,N′)nickel(II) |
| title_short |
Bis(acetato-κO)bis(pyridine-2-aldoxime-κ2
N,N′)nickel(II) |
| title_full |
Bis(acetato-κO)bis(pyridine-2-aldoxime-κ2
N,N′)nickel(II) |
| title_fullStr |
Bis(acetato-κO)bis(pyridine-2-aldoxime-κ2
N,N′)nickel(II) |
| title_full_unstemmed |
Bis(acetato-κO)bis(pyridine-2-aldoxime-κ2
N,N′)nickel(II) |
| title_sort |
bis(acetato-κo)bis(pyridine-2-aldoxime-κ2
n,n′)nickel(ii) |
| description |
In the mononuclear title compound, [Ni(CH3COO)2(C6H6N2O)2], the NiII atom is coordinated by two pyridine-2-aldoxime (PaoH) ligands and two acetate groups, with cis coordination for the pairs of identical ligands. While each acetate group binds to the NiII atom by one O atom, each PaoH chelates the NiII atom through two N atoms. The O atom on PaoH is not deprotonated and does not participate in bonding to the NiII atom. Thus, the NiII atom exhibits an octahedral environment. Intramolecular O—H⋯O hydrogen-bonding interactions and intermolecular C—H⋯O hydrogen-bonding interactions are present in the structure. Adjacent molecules pack along [100] through van der Waals forces. |
| publisher |
International Union of Crystallography |
| publishDate |
2012 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344309/ |
| _version_ |
1611527300811063296 |