Poly[tetraaquabis(μ3-oxalato-κ5 O 1,O 2:O 1′:O 1′,O 2′)(μ2-oxalato-κ4 O 1,O 2:O 1′,O 2′)dipraseodymium(III)]
In the title complex, [Pr2(C2O4)3(H2O)4]n, the two independent PrIII ions are both nine-coordinated in a distorted monocapped square-antiprismatic geometry by seven O atoms from four oxalate ligands and two water molecules. The PrIII ions are bridged by the oxalate ligands, forming a layer paralle...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2012
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343842/ |
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pubmed-3343842 |
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oai_dc |
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pubmed-33438422012-05-15 Poly[tetraaquabis(μ3-oxalato-κ5 O 1,O 2:O 1′:O 1′,O 2′)(μ2-oxalato-κ4 O 1,O 2:O 1′,O 2′)dipraseodymium(III)] Hao, Cheng-Jun Xie, Hui Metal-Organic Papers In the title complex, [Pr2(C2O4)3(H2O)4]n, the two independent PrIII ions are both nine-coordinated in a distorted monocapped square-antiprismatic geometry by seven O atoms from four oxalate ligands and two water molecules. The PrIII ions are bridged by the oxalate ligands, forming a layer parallel to (001). O—H⋯O hydrogen bonds connect the layers. International Union of Crystallography 2012-03-17 /pmc/articles/PMC3343842/ /pubmed/22589816 http://dx.doi.org/10.1107/S1600536812011014 Text en © Hao and Xie 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Hao, Cheng-Jun Xie, Hui |
| spellingShingle |
Hao, Cheng-Jun Xie, Hui Poly[tetraaquabis(μ3-oxalato-κ5 O 1,O 2:O 1′:O 1′,O 2′)(μ2-oxalato-κ4 O 1,O 2:O 1′,O 2′)dipraseodymium(III)] |
| author_facet |
Hao, Cheng-Jun Xie, Hui |
| author_sort |
Hao, Cheng-Jun |
| title |
Poly[tetraaquabis(μ3-oxalato-κ5
O
1,O
2:O
1′:O
1′,O
2′)(μ2-oxalato-κ4
O
1,O
2:O
1′,O
2′)dipraseodymium(III)] |
| title_short |
Poly[tetraaquabis(μ3-oxalato-κ5
O
1,O
2:O
1′:O
1′,O
2′)(μ2-oxalato-κ4
O
1,O
2:O
1′,O
2′)dipraseodymium(III)] |
| title_full |
Poly[tetraaquabis(μ3-oxalato-κ5
O
1,O
2:O
1′:O
1′,O
2′)(μ2-oxalato-κ4
O
1,O
2:O
1′,O
2′)dipraseodymium(III)] |
| title_fullStr |
Poly[tetraaquabis(μ3-oxalato-κ5
O
1,O
2:O
1′:O
1′,O
2′)(μ2-oxalato-κ4
O
1,O
2:O
1′,O
2′)dipraseodymium(III)] |
| title_full_unstemmed |
Poly[tetraaquabis(μ3-oxalato-κ5
O
1,O
2:O
1′:O
1′,O
2′)(μ2-oxalato-κ4
O
1,O
2:O
1′,O
2′)dipraseodymium(III)] |
| title_sort |
poly[tetraaquabis(μ3-oxalato-κ5
o
1,o
2:o
1′:o
1′,o
2′)(μ2-oxalato-κ4
o
1,o
2:o
1′,o
2′)dipraseodymium(iii)] |
| description |
In the title complex, [Pr2(C2O4)3(H2O)4]n, the two independent PrIII ions are both nine-coordinated in a distorted monocapped square-antiprismatic geometry by seven O atoms from four oxalate ligands and two water molecules. The PrIII ions are bridged by the oxalate ligands, forming a layer parallel to (001). O—H⋯O hydrogen bonds connect the layers. |
| publisher |
International Union of Crystallography |
| publishDate |
2012 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3343842/ |
| _version_ |
1611527032898846720 |