{μ-2-[4-(Benzothiazol-2-yl)benzyl]-2-azapropane-1,3-dithiolato-1:2κ4 S,S′:S,S′}bis[tricarbonyliron(I)]
The title compound, [Fe2(C16H14N2S3)(CO)6], was prepared as the biomimetic model for the active site of iron-only hydrogenase. The structure is similar to the diiron subsite of the iron-only hydrogenase active site, and contains a diiron-azadithiolate moiety in which a boat six-membered ring is fu...
Main Authors: | , , |
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Format: | Online |
Language: | English |
Published: |
International Union of Crystallography
2012
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Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297265/ |