{μ-2-[4-(Benzothia­zol-2-yl)benz­yl]-2-aza­propane-1,3-dithiol­ato-1:2κ4 S,S′:S,S′}bis­[tricarbonyl­iron(I)]

The title compound, [Fe2(C16H14N2S3)(CO)6], was prepared as the biomimetic model for the active site of iron-only hydrogenase. The structure is similar to the diiron subsite of the iron-only hydrogenase active site, and contains a diiron-aza­dithiol­ate moiety in which a boat six-membered ring is fu...

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Bibliographic Details
Main Authors: Gao, Shang, Duan, Qian, Jiang, Da-yong
Format: Online
Language:English
Published: International Union of Crystallography 2012
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297265/