Bis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ2 N 6,N 7)cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ3 N,O 2:O 3;κ3 O 3:N,O 2]
In the title compound, [Cd2(C7H3NO4)2(C13H8N4)2(H2O)2], the CdII ion is six-coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand, one N atom and one O atom from a pyridine-2,3-dicarboxylate (pdc) ligand, one O atom from another pdc ligand and one water molecule in a...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2012
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297253/ |
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pubmed-3297253 |
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oai_dc |
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pubmed-32972532012-03-12 Bis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ2 N 6,N 7)cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ3 N,O 2:O 3;κ3 O 3:N,O 2] Chen, Li-Juan Yang, Ming-Xing Huang, Hua Chen, Xiao-Hua Lin, Shen Metal-Organic Papers In the title compound, [Cd2(C7H3NO4)2(C13H8N4)2(H2O)2], the CdII ion is six-coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand, one N atom and one O atom from a pyridine-2,3-dicarboxylate (pdc) ligand, one O atom from another pdc ligand and one water molecule in a distorted octahedral geometry. Two CdII ions are bridged by a pair of pdc ligands, forming a centrosymmetric dinuclear structure. Neighboring dinuclear units are linked by the coordinated water molecules through O—H⋯N and O—H⋯O hydrogen bonds, forming a layer parallel to (011). The layers are further linked into a three-dimensional network through N—H⋯O hydrogen bonds. π–π interactions between the IP ligands further stabilize the supramolecular structure [centroid–centroid distances = 3.579 (3), 3.686 (3), 3.710 (3), 3.766 (3) and 3.841 (3) Å]. International Union of Crystallography 2012-02-17 /pmc/articles/PMC3297253/ /pubmed/22412443 http://dx.doi.org/10.1107/S160053681200579X Text en © Chen et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Chen, Li-Juan Yang, Ming-Xing Huang, Hua Chen, Xiao-Hua Lin, Shen |
| spellingShingle |
Chen, Li-Juan Yang, Ming-Xing Huang, Hua Chen, Xiao-Hua Lin, Shen Bis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ2 N 6,N 7)cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ3 N,O 2:O 3;κ3 O 3:N,O 2] |
| author_facet |
Chen, Li-Juan Yang, Ming-Xing Huang, Hua Chen, Xiao-Hua Lin, Shen |
| author_sort |
Chen, Li-Juan |
| title |
Bis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ2
N
6,N
7)cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ3
N,O
2:O
3;κ3
O
3:N,O
2] |
| title_short |
Bis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ2
N
6,N
7)cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ3
N,O
2:O
3;κ3
O
3:N,O
2] |
| title_full |
Bis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ2
N
6,N
7)cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ3
N,O
2:O
3;κ3
O
3:N,O
2] |
| title_fullStr |
Bis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ2
N
6,N
7)cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ3
N,O
2:O
3;κ3
O
3:N,O
2] |
| title_full_unstemmed |
Bis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ2
N
6,N
7)cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ3
N,O
2:O
3;κ3
O
3:N,O
2] |
| title_sort |
bis[[aqua(1h-imidazo[4,5-f][1,10]phenanthroline-κ2
n
6,n
7)cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ3
n,o
2:o
3;κ3
o
3:n,o
2] |
| description |
In the title compound, [Cd2(C7H3NO4)2(C13H8N4)2(H2O)2], the CdII ion is six-coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand, one N atom and one O atom from a pyridine-2,3-dicarboxylate (pdc) ligand, one O atom from another pdc ligand and one water molecule in a distorted octahedral geometry. Two CdII ions are bridged by a pair of pdc ligands, forming a centrosymmetric dinuclear structure. Neighboring dinuclear units are linked by the coordinated water molecules through O—H⋯N and O—H⋯O hydrogen bonds, forming a layer parallel to (011). The layers are further linked into a three-dimensional network through N—H⋯O hydrogen bonds. π–π interactions between the IP ligands further stabilize the supramolecular structure [centroid–centroid distances = 3.579 (3), 3.686 (3), 3.710 (3), 3.766 (3) and 3.841 (3) Å]. |
| publisher |
International Union of Crystallography |
| publishDate |
2012 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3297253/ |
| _version_ |
1611511541018918912 |