Methyl (2Z)-2-({N-[2-(hydroxymethyl)phenyl]-4-methylbenzenesulfonamido}methyl)-3-phenylprop-2-enoate
In the title compound, C25H25NO5S, the O atom of the hydroxy group is disordered over two positions, with occupancies of 0.820 (2) and 0.180 (2). The sulfonyl-bound benzene ring forms dihedral angles of 31.8 (1) and 60.7 (1)°, respectively, with the hydroxymethylbenzene and phenyl rings. The mol...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2012
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275177/ |
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pubmed-3275177 |
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oai_dc |
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pubmed-32751772012-02-15 Methyl (2Z)-2-({N-[2-(hydroxymethyl)phenyl]-4-methylbenzenesulfonamido}methyl)-3-phenylprop-2-enoate Madhanraj, R. Murugavel, S. Kannan, D. Bakthadoss, M. Organic Papers In the title compound, C25H25NO5S, the O atom of the hydroxy group is disordered over two positions, with occupancies of 0.820 (2) and 0.180 (2). The sulfonyl-bound benzene ring forms dihedral angles of 31.8 (1) and 60.7 (1)°, respectively, with the hydroxymethylbenzene and phenyl rings. The molecular conformation is stabilized by an intramolecular O—H⋯O hydrogen bond, generating an S(8) ring motif. The crystal packing is stabilized by intermolecular C—H⋯O hydrogen bonds and C—H⋯π interactions. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3275177/ /pubmed/22347033 http://dx.doi.org/10.1107/S1600536812000864 Text en © Madhanraj et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Madhanraj, R. Murugavel, S. Kannan, D. Bakthadoss, M. |
| spellingShingle |
Madhanraj, R. Murugavel, S. Kannan, D. Bakthadoss, M. Methyl (2Z)-2-({N-[2-(hydroxymethyl)phenyl]-4-methylbenzenesulfonamido}methyl)-3-phenylprop-2-enoate |
| author_facet |
Madhanraj, R. Murugavel, S. Kannan, D. Bakthadoss, M. |
| author_sort |
Madhanraj, R. |
| title |
Methyl (2Z)-2-({N-[2-(hydroxymethyl)phenyl]-4-methylbenzenesulfonamido}methyl)-3-phenylprop-2-enoate |
| title_short |
Methyl (2Z)-2-({N-[2-(hydroxymethyl)phenyl]-4-methylbenzenesulfonamido}methyl)-3-phenylprop-2-enoate |
| title_full |
Methyl (2Z)-2-({N-[2-(hydroxymethyl)phenyl]-4-methylbenzenesulfonamido}methyl)-3-phenylprop-2-enoate |
| title_fullStr |
Methyl (2Z)-2-({N-[2-(hydroxymethyl)phenyl]-4-methylbenzenesulfonamido}methyl)-3-phenylprop-2-enoate |
| title_full_unstemmed |
Methyl (2Z)-2-({N-[2-(hydroxymethyl)phenyl]-4-methylbenzenesulfonamido}methyl)-3-phenylprop-2-enoate |
| title_sort |
methyl (2z)-2-({n-[2-(hydroxymethyl)phenyl]-4-methylbenzenesulfonamido}methyl)-3-phenylprop-2-enoate |
| description |
In the title compound, C25H25NO5S, the O atom of the hydroxy group is disordered over two positions, with occupancies of 0.820 (2) and 0.180 (2). The sulfonyl-bound benzene ring forms dihedral angles of 31.8 (1) and 60.7 (1)°, respectively, with the hydroxymethylbenzene and phenyl rings. The molecular conformation is stabilized by an intramolecular O—H⋯O hydrogen bond, generating an S(8) ring motif. The crystal packing is stabilized by intermolecular C—H⋯O hydrogen bonds and C—H⋯π interactions. |
| publisher |
International Union of Crystallography |
| publishDate |
2012 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275177/ |
| _version_ |
1611504741473320960 |