N,N′-Dibenzyl-N′′-(2,4-difluoro­benzo­yl)-N,N′-dimethyl­phospho­ric triamide

In the title mol­ecule, C23H24F2N3O2P, the P atom is in a distorted tetra­hedral P(=O)(N)(N)2 environment, with the bond angles around the P atom in the range 106.78 (11)–114.10 (13)°. The phosphoryl and carbonyl groups, which are separated by an N atom, adopt an anti orientation relative to each ot...

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Bibliographic Details
Main Authors: Pourayoubi, Mehrdad, Shoghpour, Samad, Torre-Fernández, Laura, García-Granda, Santiago
Format: Online
Language:English
Published: International Union of Crystallography 2012
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274968/
Description
Summary:In the title mol­ecule, C23H24F2N3O2P, the P atom is in a distorted tetra­hedral P(=O)(N)(N)2 environment, with the bond angles around the P atom in the range 106.78 (11)–114.10 (13)°. The phosphoryl and carbonyl groups, which are separated by an N atom, adopt an anti orientation relative to each other. In the C(=O)NHP(=O) fragment, the P—N bond is longer [1.683 (2) Å] and the O—P—N angle is smaller [106.78 (11)°] than the other P—N bonds [1.613 (2) and 1.632 (2) Å] and O—P—N bond angles [114.10 (13) and 110.83 (12)°], respectively. The N atoms have sp 2 character. In the crystal, pairs of P=O⋯H—N hydrogen bonds form inversion dimers with R 2 2(8) ring motifs.