Butylbis(dimethylglyoximato-κ2 N,N′)(pyridine-κN)cobalt(III)1
In the title compound, [Co(C4H9)(C4H7N2O2)2(C5H5N)], which was prepared as a model complex of vitamin B12, the CoIII atom is coordinated by a butyl group, a pyridine and two N,N′-bidentate dimethylglyoximate ligands in a distorted octahedral geometry. The bis-chelating dimethylglyoximate ligands,...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2012
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274889/ |
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pubmed-3274889 |
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pubmed-32748892012-02-15 Butylbis(dimethylglyoximato-κ2 N,N′)(pyridine-κN)cobalt(III)1 Kumar, Sarvendra Thapa, Suresh Metal-Organic Papers In the title compound, [Co(C4H9)(C4H7N2O2)2(C5H5N)], which was prepared as a model complex of vitamin B12, the CoIII atom is coordinated by a butyl group, a pyridine and two N,N′-bidentate dimethylglyoximate ligands in a distorted octahedral geometry. The bis-chelating dimethylglyoximate ligands, which occupy equatorial sites, are linked by strong intramolecular O—H⋯O hydrogen bonds. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3274889/ /pubmed/22346836 http://dx.doi.org/10.1107/S1600536812000967 Text en © Kumar and Thapa 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Kumar, Sarvendra Thapa, Suresh |
| spellingShingle |
Kumar, Sarvendra Thapa, Suresh Butylbis(dimethylglyoximato-κ2 N,N′)(pyridine-κN)cobalt(III)1 |
| author_facet |
Kumar, Sarvendra Thapa, Suresh |
| author_sort |
Kumar, Sarvendra |
| title |
Butylbis(dimethylglyoximato-κ2
N,N′)(pyridine-κN)cobalt(III)1
|
| title_short |
Butylbis(dimethylglyoximato-κ2
N,N′)(pyridine-κN)cobalt(III)1
|
| title_full |
Butylbis(dimethylglyoximato-κ2
N,N′)(pyridine-κN)cobalt(III)1
|
| title_fullStr |
Butylbis(dimethylglyoximato-κ2
N,N′)(pyridine-κN)cobalt(III)1
|
| title_full_unstemmed |
Butylbis(dimethylglyoximato-κ2
N,N′)(pyridine-κN)cobalt(III)1
|
| title_sort |
butylbis(dimethylglyoximato-κ2
n,n′)(pyridine-κn)cobalt(iii)1 |
| description |
In the title compound, [Co(C4H9)(C4H7N2O2)2(C5H5N)], which was prepared as a model complex of vitamin B12, the CoIII atom is coordinated by a butyl group, a pyridine and two N,N′-bidentate dimethylglyoximate ligands in a distorted octahedral geometry. The bis-chelating dimethylglyoximate ligands, which occupy equatorial sites, are linked by strong intramolecular O—H⋯O hydrogen bonds. |
| publisher |
International Union of Crystallography |
| publishDate |
2012 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274889/ |
| _version_ |
1611504617428877312 |