Novel Cβ–Cγ Bond Cleavages of Tryptophan-Containing Peptide Radical Cations
In this study, we observed unprecedented cleavages of the Cβ–Cγ bonds of tryptophan residue side chains in a series of hydrogen-deficient tryptophan-containing peptide radical cations (M•+) during low-energy collision-induced dissociation (CID). We used CID experiments and theoretical density functi...
| Main Authors: | , , , , |
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| Format: | Online |
| Language: | English |
| Published: |
Springer-Verlag
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3264861/ |