Aqua(3-fluorobenzoato-κO)(3-fluorobenzoato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)cobalt(II)
In the title compound, [Co(C7H4FO2)2(C12H8N2)(H2O)], the CoII ion is coordinated by two O atoms from one 3-fluorobenzoate (fb) ligand and one O atom from another fb ligand, two N atoms from the 1,10-phenanthroline ligand and a water molecule in a distorted octahedral geometry. An intramolecular...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254294/ |
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pubmed-3254294 |
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oai_dc |
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pubmed-32542942012-01-18 Aqua(3-fluorobenzoato-κO)(3-fluorobenzoato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)cobalt(II) Wang, Xiao-Hui Sun, Li-Mei Metal-Organic Papers In the title compound, [Co(C7H4FO2)2(C12H8N2)(H2O)], the CoII ion is coordinated by two O atoms from one 3-fluorobenzoate (fb) ligand and one O atom from another fb ligand, two N atoms from the 1,10-phenanthroline ligand and a water molecule in a distorted octahedral geometry. An intramolecular O—H⋯O hydrogen bond occurs. Intermolecular O—H⋯O hydrogen bonds link pairs of molecules into centrosymmetric dimers. Weak intermolecular C—H⋯O and C—H⋯F hydrogen bonds and π–π interactions between the aromatic rings [shortest centroid–centroid distance = 3.4962 (2) Å] further stabilize the crystal packing. International Union of Crystallography 2011-12-07 /pmc/articles/PMC3254294/ /pubmed/22259322 http://dx.doi.org/10.1107/S1600536811051804 Text en © Wang and Sun 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Wang, Xiao-Hui Sun, Li-Mei |
| spellingShingle |
Wang, Xiao-Hui Sun, Li-Mei Aqua(3-fluorobenzoato-κO)(3-fluorobenzoato-κ2 O,O′)(1,10-phenanthroline-κ2 N,N′)cobalt(II) |
| author_facet |
Wang, Xiao-Hui Sun, Li-Mei |
| author_sort |
Wang, Xiao-Hui |
| title |
Aqua(3-fluorobenzoato-κO)(3-fluorobenzoato-κ2
O,O′)(1,10-phenanthroline-κ2
N,N′)cobalt(II) |
| title_short |
Aqua(3-fluorobenzoato-κO)(3-fluorobenzoato-κ2
O,O′)(1,10-phenanthroline-κ2
N,N′)cobalt(II) |
| title_full |
Aqua(3-fluorobenzoato-κO)(3-fluorobenzoato-κ2
O,O′)(1,10-phenanthroline-κ2
N,N′)cobalt(II) |
| title_fullStr |
Aqua(3-fluorobenzoato-κO)(3-fluorobenzoato-κ2
O,O′)(1,10-phenanthroline-κ2
N,N′)cobalt(II) |
| title_full_unstemmed |
Aqua(3-fluorobenzoato-κO)(3-fluorobenzoato-κ2
O,O′)(1,10-phenanthroline-κ2
N,N′)cobalt(II) |
| title_sort |
aqua(3-fluorobenzoato-κo)(3-fluorobenzoato-κ2
o,o′)(1,10-phenanthroline-κ2
n,n′)cobalt(ii) |
| description |
In the title compound, [Co(C7H4FO2)2(C12H8N2)(H2O)], the CoII ion is coordinated by two O atoms from one 3-fluorobenzoate (fb) ligand and one O atom from another fb ligand, two N atoms from the 1,10-phenanthroline ligand and a water molecule in a distorted octahedral geometry. An intramolecular O—H⋯O hydrogen bond occurs. Intermolecular O—H⋯O hydrogen bonds link pairs of molecules into centrosymmetric dimers. Weak intermolecular C—H⋯O and C—H⋯F hydrogen bonds and π–π interactions between the aromatic rings [shortest centroid–centroid distance = 3.4962 (2) Å] further stabilize the crystal packing. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254294/ |
| _version_ |
1611498850537701376 |