1-(5-Nitro-2-oxoindolin-3-ylidene)thiosemicarbazide
In the title molecule, C9H7N5O3S, there is an intramolecular N—H⋯O. The molecule is essentially planar, with the maximum deviation from the mean plane of the 18 non-H atoms being 0.135 (2) Å for the amine N atom. In the crystal, the molecules are connected via intermolecular N—H⋯O and N—H⋯S hydrogen...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247594/ |
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pubmed-3247594 |
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oai_dc |
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pubmed-32475942012-01-04 1-(5-Nitro-2-oxoindolin-3-ylidene)thiosemicarbazide Bandeira, Katlen C. T. Bresolin, Leandro Beck, Johannes Daniels, Jörg de Oliveira, Adriano Bof Organic Papers In the title molecule, C9H7N5O3S, there is an intramolecular N—H⋯O. The molecule is essentially planar, with the maximum deviation from the mean plane of the 18 non-H atoms being 0.135 (2) Å for the amine N atom. In the crystal, the molecules are connected via intermolecular N—H⋯O and N—H⋯S hydrogen bonds, forming two-dimensional networks lying parallel to (10). They are separated by an interplanar distance of 3.3214 (9) Å, leading to π–π interactions which stabilize the crystal structure. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3247594/ /pubmed/22219899 http://dx.doi.org/10.1107/S1600536811040293 Text en © Bandeira et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Bandeira, Katlen C. T. Bresolin, Leandro Beck, Johannes Daniels, Jörg de Oliveira, Adriano Bof |
| spellingShingle |
Bandeira, Katlen C. T. Bresolin, Leandro Beck, Johannes Daniels, Jörg de Oliveira, Adriano Bof 1-(5-Nitro-2-oxoindolin-3-ylidene)thiosemicarbazide |
| author_facet |
Bandeira, Katlen C. T. Bresolin, Leandro Beck, Johannes Daniels, Jörg de Oliveira, Adriano Bof |
| author_sort |
Bandeira, Katlen C. T. |
| title |
1-(5-Nitro-2-oxoindolin-3-ylidene)thiosemicarbazide |
| title_short |
1-(5-Nitro-2-oxoindolin-3-ylidene)thiosemicarbazide |
| title_full |
1-(5-Nitro-2-oxoindolin-3-ylidene)thiosemicarbazide |
| title_fullStr |
1-(5-Nitro-2-oxoindolin-3-ylidene)thiosemicarbazide |
| title_full_unstemmed |
1-(5-Nitro-2-oxoindolin-3-ylidene)thiosemicarbazide |
| title_sort |
1-(5-nitro-2-oxoindolin-3-ylidene)thiosemicarbazide |
| description |
In the title molecule, C9H7N5O3S, there is an intramolecular N—H⋯O. The molecule is essentially planar, with the maximum deviation from the mean plane of the 18 non-H atoms being 0.135 (2) Å for the amine N atom. In the crystal, the molecules are connected via intermolecular N—H⋯O and N—H⋯S hydrogen bonds, forming two-dimensional networks lying parallel to (10). They are separated by an interplanar distance of 3.3214 (9) Å, leading to π–π interactions which stabilize the crystal structure. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247594/ |
| _version_ |
1611497116966846464 |