N,N′-Diethyl-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide
In the title compound, C24H28N2O4S2, the dihedral angles between the central benzene ring and the pendant rings are 77.44 (11) and 79.23 (10)°, and the dihedral angle between the pendant rings is 23.31 (12)°. Both sulfonamide groups project to the same side of the central benzene ring and the molec...
Main Authors: | , , , , |
---|---|
Format: | Online |
Language: | English |
Published: |
International Union of Crystallography
2011
|
Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247432/ |
id |
pubmed-3247432 |
---|---|
recordtype |
oai_dc |
spelling |
pubmed-32474322012-01-04 N,N′-Diethyl-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide Ejaz, Khan, Islam Ullah Ahmad, Hira Harrison, William T. A. Sheikh, Tahir Ali Organic Papers In the title compound, C24H28N2O4S2, the dihedral angles between the central benzene ring and the pendant rings are 77.44 (11) and 79.23 (10)°, and the dihedral angle between the pendant rings is 23.31 (12)°. Both sulfonamide groups project to the same side of the central benzene ring and the molecule has approximate non-crystallographic mirror symmetry. One of the ethyl side chains is disordered over two sets of sites in a 0.526 (14):0.474 (14) ratio. In the crystal, inversion dimers linked by pairs of weak C—H⋯O interactions occur, generating R 2 2(28) loops. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247432/ /pubmed/22220050 http://dx.doi.org/10.1107/S1600536811040700 Text en © Ejaz et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
repository_type |
Open Access Journal |
institution_category |
Foreign Institution |
institution |
US National Center for Biotechnology Information |
building |
NCBI PubMed |
collection |
Online Access |
language |
English |
format |
Online |
author |
Ejaz, Khan, Islam Ullah Ahmad, Hira Harrison, William T. A. Sheikh, Tahir Ali |
spellingShingle |
Ejaz, Khan, Islam Ullah Ahmad, Hira Harrison, William T. A. Sheikh, Tahir Ali N,N′-Diethyl-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide |
author_facet |
Ejaz, Khan, Islam Ullah Ahmad, Hira Harrison, William T. A. Sheikh, Tahir Ali |
author_sort |
Ejaz, |
title |
N,N′-Diethyl-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide |
title_short |
N,N′-Diethyl-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide |
title_full |
N,N′-Diethyl-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide |
title_fullStr |
N,N′-Diethyl-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide |
title_full_unstemmed |
N,N′-Diethyl-N,N′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide |
title_sort |
n,n′-diethyl-n,n′-[1,3-phenylenebis(methylene)]dibenzenesulfonamide |
description |
In the title compound, C24H28N2O4S2, the dihedral angles between the central benzene ring and the pendant rings are 77.44 (11) and 79.23 (10)°, and the dihedral angle between the pendant rings is 23.31 (12)°. Both sulfonamide groups project to the same side of the central benzene ring and the molecule has approximate non-crystallographic mirror symmetry. One of the ethyl side chains is disordered over two sets of sites in a 0.526 (14):0.474 (14) ratio. In the crystal, inversion dimers linked by pairs of weak C—H⋯O interactions occur, generating R
2
2(28) loops. |
publisher |
International Union of Crystallography |
publishDate |
2011 |
url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247432/ |
_version_ |
1611497022085398528 |