4,4′-Di-tert-butyl-2,2′-[(3aRS,7aRS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl)bis(methylene)]diphenol
In the title compound, C29H42N2O2, the heterocyclic ring has a twist conformation. The cyclohexane ring adopts a chair conformation. The dihedral angle between the aromatic rings is 32.74 (6)°. The molecular conformation is stabilized by two intramolecular O—H⋯N hydrogen bonds with graph-set motif...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247337/ |
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pubmed-3247337 |
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oai_dc |
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pubmed-32473372012-01-04 4,4′-Di-tert-butyl-2,2′-[(3aRS,7aRS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl)bis(methylene)]diphenol Rivera, Augusto Pacheco, Dency José Ríos-Motta, Jaime Pojarová, Michaela Dušek, Michal Organic Papers In the title compound, C29H42N2O2, the heterocyclic ring has a twist conformation. The cyclohexane ring adopts a chair conformation. The dihedral angle between the aromatic rings is 32.74 (6)°. The molecular conformation is stabilized by two intramolecular O—H⋯N hydrogen bonds with graph-set motif S(6). The crystal packing is stabilized by C—H⋯O and C—H⋯π interactions. International Union of Crystallography 2011-10-12 /pmc/articles/PMC3247337/ /pubmed/22219955 http://dx.doi.org/10.1107/S1600536811039171 Text en © Rivera et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Rivera, Augusto Pacheco, Dency José Ríos-Motta, Jaime Pojarová, Michaela Dušek, Michal |
| spellingShingle |
Rivera, Augusto Pacheco, Dency José Ríos-Motta, Jaime Pojarová, Michaela Dušek, Michal 4,4′-Di-tert-butyl-2,2′-[(3aRS,7aRS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl)bis(methylene)]diphenol |
| author_facet |
Rivera, Augusto Pacheco, Dency José Ríos-Motta, Jaime Pojarová, Michaela Dušek, Michal |
| author_sort |
Rivera, Augusto |
| title |
4,4′-Di-tert-butyl-2,2′-[(3aRS,7aRS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl)bis(methylene)]diphenol |
| title_short |
4,4′-Di-tert-butyl-2,2′-[(3aRS,7aRS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl)bis(methylene)]diphenol |
| title_full |
4,4′-Di-tert-butyl-2,2′-[(3aRS,7aRS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl)bis(methylene)]diphenol |
| title_fullStr |
4,4′-Di-tert-butyl-2,2′-[(3aRS,7aRS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl)bis(methylene)]diphenol |
| title_full_unstemmed |
4,4′-Di-tert-butyl-2,2′-[(3aRS,7aRS)-2,3,3a,4,5,6,7,7a-octahydro-1H-1,3-benzimidazole-1,3-diyl)bis(methylene)]diphenol |
| title_sort |
4,4′-di-tert-butyl-2,2′-[(3ars,7ars)-2,3,3a,4,5,6,7,7a-octahydro-1h-1,3-benzimidazole-1,3-diyl)bis(methylene)]diphenol |
| description |
In the title compound, C29H42N2O2, the heterocyclic ring has a twist conformation. The cyclohexane ring adopts a chair conformation. The dihedral angle between the aromatic rings is 32.74 (6)°. The molecular conformation is stabilized by two intramolecular O—H⋯N hydrogen bonds with graph-set motif S(6). The crystal packing is stabilized by C—H⋯O and C—H⋯π interactions. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247337/ |
| _version_ |
1611496967166230528 |