N,N′-Dicyclopentyl-N′′,N′′-dimethylphosphoric triamide
The P atom in the title molecule, C12H26N3OP, has a distorted tetrahedral configuration: its bond angles lie in the range 101.1 (2)–119.1 (2)°. The P—N bonds to the two cyclopentylamido moieties are significantly different [1.619 (4) and 1.643 (4) Å], with the shorter bond related to an anti ori...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239040/ |
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pubmed-3239040 |
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pubmed-32390402011-12-23 N,N′-Dicyclopentyl-N′′,N′′-dimethylphosphoric triamide Raissi Shabari, Akbar Pourayoubi, Mehrdad Ghoreishi, Farnaz Vahdani, Banafsheh Organic Papers The P atom in the title molecule, C12H26N3OP, has a distorted tetrahedral configuration: its bond angles lie in the range 101.1 (2)–119.1 (2)°. The P—N bonds to the two cyclopentylamido moieties are significantly different [1.619 (4) and 1.643 (4) Å], with the shorter bond related to an anti orientation of the lone electron pair of the corresponding N atom relative to the P=O bond. The O atom of the P=O group acts as a double hydrogen-bond acceptor and is involved in two different intermolecular N—H⋯O(P) hydrogen bonds, building R 2 2(8) rings that are further linked into chains along [001]. International Union of Crystallography 2011-11-23 /pmc/articles/PMC3239040/ /pubmed/22199888 http://dx.doi.org/10.1107/S1600536811048549 Text en © Raissi Shabari et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Raissi Shabari, Akbar Pourayoubi, Mehrdad Ghoreishi, Farnaz Vahdani, Banafsheh |
| spellingShingle |
Raissi Shabari, Akbar Pourayoubi, Mehrdad Ghoreishi, Farnaz Vahdani, Banafsheh N,N′-Dicyclopentyl-N′′,N′′-dimethylphosphoric triamide |
| author_facet |
Raissi Shabari, Akbar Pourayoubi, Mehrdad Ghoreishi, Farnaz Vahdani, Banafsheh |
| author_sort |
Raissi Shabari, Akbar |
| title |
N,N′-Dicyclopentyl-N′′,N′′-dimethylphosphoric triamide |
| title_short |
N,N′-Dicyclopentyl-N′′,N′′-dimethylphosphoric triamide |
| title_full |
N,N′-Dicyclopentyl-N′′,N′′-dimethylphosphoric triamide |
| title_fullStr |
N,N′-Dicyclopentyl-N′′,N′′-dimethylphosphoric triamide |
| title_full_unstemmed |
N,N′-Dicyclopentyl-N′′,N′′-dimethylphosphoric triamide |
| title_sort |
n,n′-dicyclopentyl-n′′,n′′-dimethylphosphoric triamide |
| description |
The P atom in the title molecule, C12H26N3OP, has a distorted tetrahedral configuration: its bond angles lie in the range 101.1 (2)–119.1 (2)°. The P—N bonds to the two cyclopentylamido moieties are significantly different [1.619 (4) and 1.643 (4) Å], with the shorter bond related to an anti orientation of the lone electron pair of the corresponding N atom relative to the P=O bond. The O atom of the P=O group acts as a double hydrogen-bond acceptor and is involved in two different intermolecular N—H⋯O(P) hydrogen bonds, building R
2
2(8) rings that are further linked into chains along [001]. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3239040/ |
| _version_ |
1611494480784916480 |