μ-Oxido-bis[chlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2 N,N′)dioxidomolybdenum(VI)] 0.2-hydrate
The title hydrate, [Mo2Cl2O5(C18H24N2)2]·0.2H2O, has been isolated as the oxidation product of [Mo(η3-C3H5)Cl(CO)2(di-t-Bu-bipy)] (where di-t-Bu-bipy is 4,4′-di-tert-butyl-2,2′-bipyridine). A μ-oxide ligand bridges two similar MoCl(di-t-Bu-bipy)O2 units, having the terminal oxide ligands mutually ci...
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| Format: | Online |
| Language: | English |
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International Union of Crystallography
2011
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238648/ |
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pubmed-3238648 |
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pubmed-32386482011-12-23 μ-Oxido-bis[chlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2 N,N′)dioxidomolybdenum(VI)] 0.2-hydrate Gomes, Ana C. Fernandes, José A. Gamelas, Carla A. Gonçalves, Isabel S. Almeida Paz, Filipe A. Metal-Organic Papers The title hydrate, [Mo2Cl2O5(C18H24N2)2]·0.2H2O, has been isolated as the oxidation product of [Mo(η3-C3H5)Cl(CO)2(di-t-Bu-bipy)] (where di-t-Bu-bipy is 4,4′-di-tert-butyl-2,2′-bipyridine). A μ-oxide ligand bridges two similar MoCl(di-t-Bu-bipy)O2 units, having the terminal oxide ligands mutually cis, and the chloride and μ-oxide trans to each other. In the binuclear complex, the coordination geometries of the metal atoms can be described as highly distorted octahedra. Individual complexes co-crystallize with a partially occupied water molecule of crystallization (occupancy factor = 0.20; H atoms not located), with the crystal packing being mediated by the need to effectively fill the available space. A number of weak C—H⋯O and C—H⋯Cl interactions are present. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238648/ /pubmed/22199539 http://dx.doi.org/10.1107/S1600536811046952 Text en © Gomes et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Gomes, Ana C. Fernandes, José A. Gamelas, Carla A. Gonçalves, Isabel S. Almeida Paz, Filipe A. |
| spellingShingle |
Gomes, Ana C. Fernandes, José A. Gamelas, Carla A. Gonçalves, Isabel S. Almeida Paz, Filipe A. μ-Oxido-bis[chlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2 N,N′)dioxidomolybdenum(VI)] 0.2-hydrate |
| author_facet |
Gomes, Ana C. Fernandes, José A. Gamelas, Carla A. Gonçalves, Isabel S. Almeida Paz, Filipe A. |
| author_sort |
Gomes, Ana C. |
| title |
μ-Oxido-bis[chlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2
N,N′)dioxidomolybdenum(VI)] 0.2-hydrate |
| title_short |
μ-Oxido-bis[chlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2
N,N′)dioxidomolybdenum(VI)] 0.2-hydrate |
| title_full |
μ-Oxido-bis[chlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2
N,N′)dioxidomolybdenum(VI)] 0.2-hydrate |
| title_fullStr |
μ-Oxido-bis[chlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2
N,N′)dioxidomolybdenum(VI)] 0.2-hydrate |
| title_full_unstemmed |
μ-Oxido-bis[chlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2
N,N′)dioxidomolybdenum(VI)] 0.2-hydrate |
| title_sort |
μ-oxido-bis[chlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2
n,n′)dioxidomolybdenum(vi)] 0.2-hydrate |
| description |
The title hydrate, [Mo2Cl2O5(C18H24N2)2]·0.2H2O, has been isolated as the oxidation product of [Mo(η3-C3H5)Cl(CO)2(di-t-Bu-bipy)] (where di-t-Bu-bipy is 4,4′-di-tert-butyl-2,2′-bipyridine). A μ-oxide ligand bridges two similar MoCl(di-t-Bu-bipy)O2 units, having the terminal oxide ligands mutually cis, and the chloride and μ-oxide trans to each other. In the binuclear complex, the coordination geometries of the metal atoms can be described as highly distorted octahedra. Individual complexes co-crystallize with a partially occupied water molecule of crystallization (occupancy factor = 0.20; H atoms not located), with the crystal packing being mediated by the need to effectively fill the available space. A number of weak C—H⋯O and C—H⋯Cl interactions are present. |
| publisher |
International Union of Crystallography |
| publishDate |
2011 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238648/ |
| _version_ |
1611494266988658688 |